01440nas a2200193   4500008004100000022001400041245017400055210006900229260011000298300001400408490000700422520055700429100002400986700002001010700002501030700003201055700002801087856013101115       2015                        eng d  a1144-054600aEnvironmentally friendly route for grafting of molybdenum carbonyl onto a diaminosilane-modified SBA-15 molecular sieve and its catalytic behaviour in olefin epoxidation0 aEnvironmentally friendly route for grafting of molybdenum carbon  aTHOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLANDbROYAL SOC CHEMISTRYcFEB  a3758-37640 v393 a<p>A simple route has been established for grafting molybdenum carbonyl onto the surface of a diaminosilane-modified SBA-15 molecular sieve. The successful grafting of the molybdenum carbonyl species onto diamine-functionalized SBA-15 was evident from FT-IR studies. The resultant molybdenum-carbonyl-complex-grafted SBA-15 (SBA-DA-Mo) materials show promising activity for the epoxidation of various olefins with good conversion (90-95%) and the formation of epoxide as the major product. The catalytic activity remains constant over several runs.</p>1 aBaskaran, Thangaraj1 aKumaravel, Raju1 aChristopher, Jayaraj1 aAjithkumar, Thalasseril, G.1 aSakthivel, Ayyamperumal  uhttps://library.ncl.res.in/content/environmentally-friendly-route-grafting-molybdenum-carbonyl-diaminosilane-modified-sba-15-0