01298nas a2200205   4500008004100000022001400041245013100055210006900186260011000255300001600365490000700381520043700388100002800825700002600853700002000879700001600899700003000915700001900945856012800964       2013                        eng d  a1359-734500aRationally designed CuFe2O4-mesoporous Al2O3 composite towards stable performance of high temperature water-gas shift reaction0 aRationally designed CuFe2O4mesoporous Al2O3 composite towards st  aTHOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLANDbROYAL SOC CHEMISTRYcJUL  a11257-112590 v493 a<p>High temperature water-gas shift reaction was demonstrated for the first time on a CuFe2O4-mesoporous alumina nanocomposite between 350 and 550 degrees C with 70-80% CO-conversion using simulated waste derived syngas under realistic conditions. Despite high Al-content, the catalyst exhibited stable activity, which was attributed to the nano-architectured robust porous nature of alumina integrated with surrounding CuFe2O4.</p>1 aSubramanian, Vijayanand1 aGnanakumar, Edwin, S.1 aJeong, Dae-Woon1 aHan, Won-Bi1 aGopinath, Chinnakonda, S.1 aRoh, Hyun-Seog  uhttps://library.ncl.res.in/content/rationally-designed-cufe2o4-mesoporous-al2o3-composite-towards-stable-performance-high-002129nas a2200253   4500008004100000022001400041245012800055210006900183260007700252300001400329490000600343520121900349653001301568653001101581653001501592653001301607653001401620100002101634700002001655700002501675700001901700700002901719856012701748       2014                        eng d  a1867-388000aEffect of composition and pretreatment parameters on activity and stability of Cu-Al catalysts for water-gas shift reaction0 aEffect of composition and pretreatment parameters on activity an  aBOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANYbWILEY-V C H VERLAG GMBHcJUN  a1698-17060 v63 a<p>We investigated various Cu species responsible for highly efficient Cu-Al oxide catalyst for the water-gas shift reaction (WGSR). The formation of various Cu species was achieved by systematically varying the Cu-Al composition in the coprecipitated mixed Cu-Al oxides. The Cu-Al composition of 70:30 (Cu-Al-7) was the best for WGSR using the reformate gas composition. In addition, the Cu-Al-7 catalyst reduced under 100% H-2, was relatively stable with time on stream of 100 h, at higher gas hourly space velocity of 36201 h(-1). The structural investigation of our coprecipitated catalysts with varying Cu-Al compositions revealed the formation of nonzero oxidation state copper and metallic Cu to be essential for the observed WGSR activity. In addition, the highest activity and stability of Cu-Al-7 catalysts reduced under 100% H-2 at lower temperature was attributed to particle-size stabilization and a lower extent of Cu aggregation by Cu2O and boehmite phases, respectively, along with the formation of various Cu species during the activation protocol for 12 h. Complete CO2 selectivity without methanation was observed for all the Cu-Al compositions irrespective of their pretreatment conditions.</p>10aaluminum10aCopper10afuel cells10aHydrogen10areduction1 aMane, Rasika, B.1 aJeong, Dae-Woon1 aMalawadkar, Atul, V.1 aRoh, Hyun-Seog1 aRode, Chandrashekhar, V.  uhttps://library.ncl.res.in/content/effect-composition-and-pretreatment-parameters-activity-and-stability-cu-al-catalysts-001790nas a2200193   4500008004100000022001400041245012100055210006900176260011000245300001600355490000600371520098900377100001401366700002201380700001801402700001901420700002901439856012801468       2014                        eng d  a2046-206900aSolvothermal synthesis of mesoporous manganese oxide with enhanced catalytic activity for veratryl alcohol oxidation0 aSolvothermal synthesis of mesoporous manganese oxide with enhanc  aTHOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLANDbROYAL SOC CHEMISTRYcAPR  a19450-194550 v43 a<p>Catalyst activities of manganese and cobalt oxides prepared by solvothermal and co-precipitation methods were studied for veratryl alcohol oxidation. Manganese oxides showed higher activity performance than that of cobalt oxides irrespective of the method of preparation. The solvothermal method yielded mesoporous manganese oxide without using any template giving mixed phases of monoclinic Mn5O8 and hausmannite Mn3O4. The mesoporous manganese oxide exhibited excellent activity for liquid phase aerobic oxidation of veratryl alcohol under base free conditions, with 90% conversion and almost complete selectivity towards veratraldehyde. The detailed characterization results on morphology, size and composition of the prepared mesoporous manganese oxide obtained by XRD, XPS, H-2-TPR, N-2 adsorption-desorption isotherms, FESEM and HR-TEM techniques were used to understand the role of morphological and structural features in enhancement of the observed catalytic activity.</p>1 aJha, Ajay1 aChandole, Tejansh1 aPandya, Rajan1 aRoh, Hyun-Seog1 aRode, Chandrashekhar, V.  uhttps://library.ncl.res.in/content/solvothermal-synthesis-mesoporous-manganese-oxide-enhanced-catalytic-activity-veratryl-001811nas a2200217   4500008004100000022001400041245008200055210006900137260011000206300001400316490000600330520101100336100001401347700002001361700001701381700001801398700001801416700002901434700001901463856011101482       2015                        eng d  a2044-475300aHydrogen production by the water-gas shift reaction using CuNi/Fe2O3 catalyst0 aHydrogen production by the watergas shift reaction using CuNiFe2  aTHOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLANDbROYAL SOC CHEMISTRYcFEB  a2752-27600 v53 a<p>Incorporation of both Cu and Ni together into the crystalline lattice of Fe2O3 results in a significant increase in the catalytic activity and also suppresses the methanation reaction in the high-temperature water-gas shift (HT-WGS) reaction. CuNi/Fe2O3 exhibited the highest CO conversion with negligible CH4 selectivity at the extremely high GHSV of 101 000 h(-1) (X-CO = 85% at 400 degrees C). The high activity of CuNi/Fe2O3 catalyst is mainly due to the increase in the lattice strain and the decrease in the binding energy of lattice oxygen. In addition, X-ray photoelectron spectroscopy (XPS) results provide direct evidence for the formation of surface CuNi alloy, which plays a critical role in suppressing the methanation reaction. The detailed characterization by powder X-ray diffraction (XRD), XPS, BET, and H-2 temperature-programmed reduction (TPR) techniques was used to understand the role of dopants on host iron oxides in the enhancement of catalytic activity for HT-WGS reaction.</p>1 aJha, Ajay1 aJeong, Dae-Woon1 aShim, Jae-Oh1 aJang, Won-Jun1 aLee, Yeol-Lim1 aRode, Chandrashekhar, V.1 aRoh, Hyun-Seog  uhttps://library.ncl.res.in/content/hydrogen-production-water-gas-shift-reaction-using-cunife2o3-catalyst-001786nas a2200193   4500008004100000022001400041245008700055210006900142260011000211300001400321490000600335520103100341100001401372700002001386700001801406700002901424700001901453856012001472       2015                        eng d  a2046-206900aMesoporous NiCu-CeO2 oxide catalysts for high-temperature water-gas shift reaction0 aMesoporous NiCuCeO2 oxide catalysts for hightemperature watergas  aTHOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLANDbROYAL SOC CHEMISTRYcNOV  a1430-14370 v53 a<p>Mesoporous NiCu-CeO2 oxide catalysts were synthesized by using the evaporation-induced self-assembly method applied to the high-temperature, water-gas shift reaction (HT-WGS) between 350 to 550 degrees C. Nickel and copper loadings on mesoporous ceria were tailored to achieve high activity and selectivity by suppressing methane formation in HT-WGS. Among the prepared catalysts, NiCu(1 : 4)-CeO2 exhibited the highest selectivity to CO2 and H-2 with 85% CO conversion at a very high GHSV of 83 665 h(-1). The higher activity of the catalysts was due to the mesoporous architecture, which provides more accessible active sites for the WGS reaction. Powder X-ray diffraction (XRD), small angle X-ray scattering (SAXS), N-2-adsorption/desorption isotherm, high-resolution transmission electron microscopy (HR-TEM), and H-2-temperature-programmed reduction (TPR) techniques were used to understand the role of mesoporosity and bimetallic composition of various NiCu-CeO2 oxides in enhancing catalytic activity for HT-WGS.</p>1 aJha, Ajay1 aJeong, Dae-Woon1 aJang, Won-Jun1 aRode, Chandrashekhar, V.1 aRoh, Hyun-Seog  uhttps://library.ncl.res.in/content/mesoporous-nicu-ceo2-oxide-catalysts-high-temperature-water-gas-shift-reaction-001904nas a2200289   4500008004100000022001400041245012400055210006900179260007300248300001000321490000800331520090700339653000901246653001501255653001901270653002101289653002001310100001401330700002001344700001801364700001801382700001701400700002001417700002901437700001901466856012901485       2016                        eng d  a0926-860X00aChromium free high temperature water-gas shift catalyst for the production of hydrogen from waste derived synthesis gas0 aChromium free high temperature watergas shift catalyst for the p  aPO BOX 211, 1000 AE AMSTERDAM, NETHERLANDSbELSEVIER SCIENCE BVcJUL  a21-310 v5223 a<p>A comparative study between monometallic (Me-CeO2, Me =Zn, Cu, Fe and Co) and Ni-doped bimetallic (Me-Ni-CeO2) catalysts has been performed in the high temperature water-gas shift (HT-WGS) reaction using waste derived synthesis gas. Experimental results revealed that Me-Ni-CeO2 exhibited higher catalytic performance than simple Me-CeO2 catalysts. Within the Me-Ni-CeO2 series, Co-Ni-CeO2 exhibited excellent and stable catalytic performance (CO conversion &gt; 90%) at a very high GHSV of 143,000 h(-1). The existence of high" concentration of Ce3+ ions and oxygen vacancies on the catalyst surface were responsible for the increased WGS activity of Co-Ni-CeO2. In addition, Co-Ni-CeO2 maintains a stable performance for 50 h. However, commercial Fe2O3-Cr2O3 catalyst showed a steep decline from their initial CO conversion values 15-10% within 5 h. (C) 2016 Elsevier B.V. All rights reserved.</p>10aCeO210aCo-Ni-CeO210aLattice strain10aoxygen vacancies10aWater-gas shift1 aJha, Ajay1 aJeong, Dae-Woon1 aLee, Yeol-Lim1 aJang, Won-Jun1 aShim, Jae-Oh1 aJeon, Kyung-Won1 aRode, Chandrashekhar, V.1 aRoh, Hyun-Seog  uhttps://library.ncl.res.in/content/chromium-free-high-temperature-water-gas-shift-catalyst-production-hydrogen-waste-derived01879nas a2200169   4500008004100000245010200041210006900143260000800212300001200220490000800232520125300240100002101493700002401514700001901538700002901557856012301586       2018                        eng d00aBifunctional role of Pd/MMT-K 10 catalyst in direct transformation of furfural to 1,2-pentanediol0 aBifunctional role of PdMMTK 10 catalyst in direct transformation  cJUL  a195-2010 v3093 a<p>The acid functionality of montmorillonite clay K 10 (MMT-K 10) was found to play a key role to give 1,2-pentanediol (1,2-PeDO) in Pd catalysed furfural hydrogenation. Among various Pd loadings on MMT-K 10, 3% Pd/MMT-K 10 catalyst exhibited excellent performance giving almost complete conversion of FFR and the highest selectivity of 66% to 1,2-PeDO. Py-IR of the catalyst evidenced the presence of Brønsted acidity which was responsible in C5-O cleavage of furan ring after the formation of furfuryl alcohol which is the first step intermediate in FFR hydrogenation. At a lower temperature of 140 °C, highest selectivity of 56% was achieved for FAL while increase in temperature to 220 °C, enhanced the selectivity to 1,2-PeDO. Keeping the temperature constant at 220 °C, with increase in H2 pressure from 500 to 750 psig, resulted in decrease in 1,2-PeDO selectivity from 66 to 34% with proportionate increase in THFAL selectivity. Thus as per the requirement, the product selectivities can be tailored by varying the reaction parameters suitably. Several control experiments were also performed the results of which combined with the characterization data allowed to propose a plausible reaction pathway for the formation of 1,2-PeDO.</p>1 aDate, Nandan, S.1 aChikate, Rajeev, C.1 aRoh, Hyun-Seog1 aRode, Chandrashekhar, V.  uhttps://library.ncl.res.in/content/bifunctional-role-pdmmt-k-10-catalyst-direct-transformation-furfural-12-pentanediol01902nas a2200301   4500008004100000022001400041245013000055210006900185260000900254300001000263490000800273520089400281653002501175653001201200653003701212653002501249653001401274653003201288100001801320700001401338700001801352700001701370700002901387700002001416700002001436700001901456856012501475       2018                        eng d  a0926-860X00aEffect of alkali and alkaline earth metal on Co/CeO2 catalyst for the water gas shift reaction of waste derived synthesis gas0 aEffect of alkali and alkaline earth metal on CoCeO2 catalyst for  cFEB   a63-700 v5513 a<p>We prepared a series of alkali (Na and K) and alkaline earth metal (Ca and Ba) promoted Co/CeO2 catalysts to investigate the effect of the promoter on the catalytic performance of the catalyst in the high-temperature water gas shift (WGS) reaction of waste derived synthesis gas. Interestingly, alkali metal promoted catalysts deactivated rapidly compared to alkaline earth metal promoted catalysts. Alkaline earth metal promoted catalysts showed relatively higher stability (&gt;50 h) even at a very high gas hourly space velocity of 143,000 h(-1). X-ray diffraction (XRD) and transmission electron microscopy (TEM) results reveal that the higher stability of the alkaline earth metal promoted catalysts was due to the strong resistance to sintering, showing a relatively small crystallite size of metallic cobalt compared to the alkali metal promoted catalysts after WGS reaction.</p>10aAlkaline earth metal10aCo/CeO210aHigh temperature water-gas shift10aSintering resistance10astability10aWaste derived synthesis gas1 aLee, Yeol-Lim1 aJha, Ajay1 aJang, Won-Jun1 aShim, Jae-Oh1 aRode, Chandrashekhar, V.1 aJeon, Byong-Hun1 aBae, Jong, Wook1 aRoh, Hyun-Seog  uhttps://library.ncl.res.in/content/effect-alkali-and-alkaline-earth-metal-coceo2-catalyst-water-gas-shift-reaction-waste01636nas a2200265   4500008004100000022001300041245010800054210006900162260000800231300001000239490000800249520077800257100001701035700001701052700001801069700002001087700001701107700001801124700001501142700002001157700002001177700002901197700001901226856012501245       2018                        eng d  a0920586100aEffect of titration time on the catalytic performance of Cu/CeO2 catalysts for water-gas shift reaction0 aEffect of titration time on the catalytic performance of CuCeO2   cJUL  a83-880 v3093 aWe herein report the preparation of ceria (CeO2) via a simple precipitation method for use as a catalyst support in the water-gas shift (WGS) reaction. More specifically, we optimized the titration time required to obtain highly active CeO2-supported catalysts for the WGS reaction. As such, Cu was employed as the active metal coupled with the CeO2 support. Notably, the CeO2-0 supported Cu catalyst (where the precipitant was immediately injected into a cerium nitrate solution) exhibited the highest CO conversion at a gas hourly space velocity of 36,050 h(-1). This high catalytic activity of the Cu/CeO2-0 catalyst was mainly due to its high Brunauer-Emmett-Teller (BET) surface area, enhanced Cu dispersion, high number of oxygen vacancies, and enhanced reducibility.1 aNa, Hyun-Suk1 aShim, Jae-Oh1 aJang, Won-Jun1 aJeon, Kyung-Won1 aKim, Hak-Min1 aLee, Yeol-Lim1 aLee, Da-We1 aYoo, Seong-Yeun1 aBae, Jong, Wook1 aRode, Chandrashekhar, V.1 aRoh, Hyun-Seog  uhttps://library.ncl.res.in/content/effect-titration-time-catalytic-performance-cuceo2-catalysts-water-gas-shift-reaction01971nas a2200229   4500008004100000022001400041245007800055210006900133260000800202300001100210490000800221520123500229653001001464653001201474653002701486653001701513653002401530100003201554700001901586700002901605856010701634       2023                        eng d  a0926-860X00aSelective oxidation of 5-HMF to DFF over alkali promoted Mn nanocomposite0 aSelective oxidation of 5HMF to DFF over alkali promoted Mn nanoc  cJUN  a1191800 v6593 a<p>
	Various compositions of Cs promoted Mn catalysts were synthesized and investigated for selective oxidation of 5HMF to DFF, among which Mn-Cs(80:20) was found to be most efficient giving 91 % conversion of 5-HMF and 99 % selectivity to DFF. Detail characterization like N2-sorption, BET surface area, TG-DTA, XRD, XPS, FE-SEM-EDX, TEM, HR-TEM, CO2-TPD, H2-TPR, O2-TPO, FTIR, Raman spectra and CH3OH-IR were done to establish structureactivity correlation. Enhanced surface area, porosity, thermal stability, dual morphologies were observed due to inclusion of Cs in Mn lattice domain which further enhanced the crystallinity, and oxygen diffusion on the surface. Mixed morphologies comprising nanoparticles (4-5 nm) and nanocubes (50-60 nm) were observed with enhanced redox potential and reduced work function due to weakening of Mn-O bonds. Significant increase in the basicity of catalyst, interfacial redox properties and lattice oxygen led to highly efficient oxidation of 5-HMF to DFF via Mars-van Krevelen mechanism at relatively milder conditions i.e. T = 90 degrees C and PO2= 200 psig. The catalyst was easily recyclable up to 7 times with minor loss in activity which was regenerated heat treatment protocol.</p>
10a5-HMF10aBiomass10aheterogeneous catalyst10apolyurethane10aSelective oxidation1 aSolanki, Bhanupratap, Singh1 aRoh, Hyun-Seog1 aRode, Chandrashekhar, V.  uhttps://library.ncl.res.in/content/selective-oxidation-5-hmf-dff-over-alkali-promoted-mn-nanocomposite