02741nas a2200325   4500008004100000022001400041245014700055210006900202260000800271300001100279490000800290520162800298653002601926653001601952653001501968653001601983100002701999700002902026700003202055700001902087700001802106700002502124700001902149700003702168700002202205700002302227700001902250700001802269856012802287       2024                        eng d  a0959-652600aExtraction, characterization, and life cycle assessment of nanosilica from millet husk:  sustainable alternative with low environmental impact0 aExtraction characterization and life cycle assessment of nanosil  cFEB  a1409240 v4423 a<p>
	Eco-friendly approaches for silica production are highly researched to respond increasing industrial demand for bio-nanofillers. Herein, nanosilica of 10-20 nm with mesoporosity was obtained through a mild oxalic acid pre-treatment of millet husk, followed by calcination at 700 degrees C for 2 h. Compared with commercial precipitated silica (CS) and millet husk ash (MHA) directly obtained by calcination of the husk, the pre-treated silica (MHS) had higher purity, revealed using EDX spectroscopy. Moreover, FTIR and Si-29 NMR showed a higher condensation degree in MHS with 73% of Q4 siloxane bonds vs 4% in MHA. The release of the metal and organic impurities from the husk also allows to reduce the crystallinity of MHS, and to increase the specific surface area from 82 m(2)/g in MHA to 238 m(2)/g in MHS. The type II N-2 adsorption-desorption isotherms of MHA and MHS indicate aggregates of non-porous silica particles. MHS also demonstrated remarkable thermal resilience. According to the LCA analysis, MHS has a 40% lower impact on global warming, a 38% lower impact on human carcinogenic toxicity, and a 38% lower impact on terrestrial acidification compared to rice husk nanosilica. This research thus addresses sustainability challenges by repurposing millet husks, which are readily available due to continuous millet cultivation, particularly in India. By reducing the ecological impact of husk disposal through burning, this study offers an economically viable technology for high-purity silica production, aligning with global efforts to combat climate change and promote sustainable practices.</p>
10aLife cycle assessment10aMillet husk10aNanosilica10aOxalic acid1 aDominic, C., D. Midhun1 aRosa, Derval, dos Santos1 aBarbosa, Rennan, Felix da S1 aAnagha, O., V.1 aNeenu, K., V.1 aBegum, P., M. Sabura1 aKumar, Aswathy1 aParameswaranpillai, Jyotishkumar1 aSiriwong, Chomsri1 aAjithkumar, T., G.1 aShelke, Ankita1 aPasc, Andreea  uhttps://library.ncl.res.in/content/extraction-characterization-and-life-cycle-assessment-nanosilica-millet-husk-sustainable