08872nas a2200229 4500008004100000245014300041210006900184260000800253300001200261490000700273520796300280653000608243653007708249653004808326100002308374700002508397700002408422700002308446700002408469700002108493856012808514 2022 eng d00aSynthesis, crystal structure and Hirshfeld surface analysis of a zinc(II) coordination polymer of 5-phenyl-1,3,4-oxa­diazole-2-thiol­ate0 aSynthesis crystal structure and Hirshfeld surface analysis of a  cAUG a794-7970 v873 a

A new zinc coordination polymer with 5-phenyl-1,3,4-oxa­diazole-2-thiol­ate, namely, catena-poly[zinc(II)-bis­(μ2-5-phenyl-1,3,4-oxa­diazole-2-thiol­ato)-κ2N3:S;κ2S:N3], [Zn(C8H5N2OS)2]n, was synthesized. The single-crystal X-ray diffraction analysis shows that the polymeric structure crystallizes in the centrosymmetric monoclinic C2/c space group. The ZnII atom is coordinated to two S and two N atoms from four crystallographically independent (L) ligands, forming zigzag chains along the [001] direction. This polymer complex forms an eight-membered [Zn–S–C–N–Zn–S–C–N] chair-like ring with two ZnII atoms and two ligand mol­ecules. On the Hirshfeld surface, the largest contributions come from the short contacts such as van der Waals forces, including H⋯H, C⋯H and S⋯H. Inter­actions including N⋯H, O⋯H and C⋯C contacts were also observed; however, their contribution to the overall stability of the crystal lattice is minor.

10a310a4-oxa­diazole-2-thiol; coordination polymer; Hirshfeld surface analysis10acrystal structure; zinc complex; 5-phenyl-11 aPirimova, Mehribon1 aTorambetov, Batirbay1 aKadirova, Shakhnoza1 aZiyaev, Abdukhakim1 aGonnade, Rajesh, G.1 aAshurov, Jamshid uhttps://library.ncl.res.in/content/synthesis-crystal-structure-and-hirshfeld-surface-analysis-zincii-coordination-polymer-5