02331nas a2200253   4500008004100000022001400041245014000055210006900195260000800264300001000272490000700282520143000289653001401719653001701733653002501750653001301775653002701788653001301815653003701828100002201865700002401887700003601911856013001947       2023                        eng d  a1615-684600aLow-temperature preferential CO oxidation in a hydrogen-rich stream over Pt-NaY and modified Pt-NaY catalysts for fuel cell application0 aLowtemperature preferential CO oxidation in a hydrogenrich strea  cFEB  a15-280 v233 a<p>
	Preferential oxidation of CO (CO-PROX) in the hydrogen-rich stream has been carried out over Pt-NaY catalysts containing various Pt loadings along with Fe, Co, and Au. Catalysts have been characterized with inductively coupled plasma-atomic emission spectroscopy, Brunauer, Emmett, and Teller surface area, X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, temperature programmed reduction, and Pt dispersion. CO-PROX activities and CO oxidation selectivities are observed to increase with an increase in Pt content. Pt-NaY catalyst with 0.75 wt.% Pt loading shows maximum CO-PROX activity at low temperatures. An increase in space velocity decreases the CO and O-2 conversions, but CO oxidation selectivity increases. A decrease in activity is observed when reformat gas contains around 20% H2O. During the stability test, no change in CO and O-2 conversions is observed, but a small increase in the CO oxidation selectivity is noticed after 10 h indicating that the Pt-NaY catalyst is a promising candidate for CO-PROX reaction in a hydrogen-rich stream. The Pt-Fe-NaY catalyst shows better activity than the Pt-NaY catalyst but starts deactivating after 10 h. However, activity is observed to decrease over Pt-Co-NaY and Pt-Au-NaY catalysts. Pt-Fe-NaY catalyst with 0.75 and 0.35 wt.% Pt and Fe, respectively, shows better CO-PROX activity at a temperature of 75 degrees C.</p>
10acatalysis10aCO oxidation10aexperimental results10aflow bed10aFuel Cell Applications10aHydrogen10aX-ray photoelectron spectroscopy1 aMalwadkar, Sachin1 aBera, Parthasarathi1 aSatyanarayana, Chilukuri, V. V.  uhttps://library.ncl.res.in/content/low-temperature-preferential-co-oxidation-hydrogen-rich-stream-over-pt-nay-and-modified-pt