02139nas a2200229   4500008004100000022001400041245015600055210006900211260009200280300001400372490000600386520124100392653001701633653001801650653001901668653002101687100002501708700001401733700001701747700001501764856013001779       2005                        eng d  a1533-488000aBiosynthesis of gold and silver nanoparticles using emblica officinalis fruit extract, their phase transfer and transmetallation in an organic solution0 aBiosynthesis of gold and silver nanoparticles using emblica offi  a26650 THE OLD RD, STE 208, VALENCIA, CA 91381-0751 USAbAMER SCIENTIFIC PUBLISHERScOCT  a1665-16710 v53 a<p>The design, synthesis and characterization of biologically synthesized nanomaterials have become an area of significant interest. In this paper, we report the extracellular synthesis of gold and silver nanoparticles using Emblica Officinalis (amla, Indian Gooseberry) fruit extract as the reducing agent to synthesize Ag and Au nanoparticles, their subsequent phase transfer to an organic solution and the transmetallation reaction of hydrophobized silver nanoparticles with hydrophobized chloroaurate ions. On treating aqueous silver sulfate and chloroauric acid solutions with Emblica Officinalis fruit extract, rapid reduction of the silver and chloroaurate ions is observed leading to the formation of highly stable silver and gold nanoparticles in solution. Transmission Electron Microscopy analysis of the silver and gold nanoparticles indicated that they ranged in size from 10 to 20 nm and 15 to 25 nm respectively. Ag and Au nanoparticles thus synthesized were then phase transferred into an organic solution using a cationic surfactant octadecylamine. Transmetallation reaction between hydrophobized silver nanoparticles and hydrophobized chloroaurate ions in chloroform resulted in the formation of gold nanoparticles.</p>10aBiosynthesis10aNanomaterials10aPhase transfer10aTransmetallation1 aAnkamwar, Balaprasad1 aDamle, C.1 aAhmad, Absar1 aSastry, M.  uhttps://library.ncl.res.in/content/biosynthesis-gold-and-silver-nanoparticles-using-emblica-officinalis-fruit-extract-their-000799nas a2200241   4500008004100000022001400041245007100055210006900126260007700195300001200272490000600284653001100290653001700301653001500318653001200333653001800345100001700363700001700380700002600397700001500423700001400438856010500452       2005                        eng d  a1613-681000aExtracellular biosynthesis of bimetallic Au-Ag alloy nanoparticles0 aExtracellular biosynthesis of bimetallic AuAg alloy nanoparticle  aPO BOX 10 11 61, D-69451 WEINHEIM, GERMANYbWILEY-V C H VERLAG GMBHcMAY  a517-5200 v110aalloys10aBiosynthesis10acomposites10aenzymes10aNanoparticles1 aSenapati, S.1 aAhmad, Absar1 aKhan, Mohammad, Islam1 aSastry, M.1 aKumar, R.  uhttps://library.ncl.res.in/content/extracellular-biosynthesis-bimetallic-au-ag-alloy-nanoparticles-002201nas a2200265   4500008004100000022001400041245010700055210006900162260009500231300001000326490000600336520126700342653001701609653001201626653001101638653000901649653002301658653001801681100001701699700002501716700002601741700001701767700001901784856013201803       2005                        eng d  a1550-703300aExtra-/intracellular biosynthesis of gold nanoparticles by an alkalotolerant fungus, trichothecium sp.0 aExtraintracellular biosynthesis of gold nanoparticles by an alka  a25650 NORTH LEWIS WAY, STEVENSON RANCH, CA 91381-1439 USAbAMER SCIENTIFIC PUBLISHERScMAR  a47-530 v13 a<p>The development of reliable, eco-friendly processes for the synthesis of nanoscale materials is an important aspect of nanotechnology. As part of our ongoing investigation into the use of fungi for nanoparticle synthesis, we report herein that depending on the reaction conditions of the fungus Trichothecium sp. with aqueous gold ions, gold nanoparticle synthesis can be controlled to occur either within the biomass or extracellularly. Moreover, we have found that reaction of gold ions with the Trichothecium sp. fungal biomass under stationary conditions results in the rapid extracellular formation of gold nanoparticles of spherical, rod-like and triangular morphology whereas reaction of the biomass under shaking conditions resulted in intracellular growth of the nanoparticles. It is believed that on changing the reaction conditions of the fungus with gold ions, the enzymes and proteins which are being released into the medium under stationary conditions do not get released under shaking conditions resulting in the formation of extracellular or intracellular gold nanoparticles respectively. The gold nanoparticles are not toxic to the cells and the cells continued to grow after the biosynthesis of the gold nanoparticles in both the cases.</p>10aBiosynthesis10aenzymes10aFungus10aGold10aMorphology Control10aNanoparticles1 aAhmad, Absar1 aSenapati, Satyajyoti1 aKhan, Mohammad, Islam1 aKumar, Rajiv1 aSastry, Murali  uhttps://library.ncl.res.in/content/extra-intracellular-biosynthesis-gold-nanoparticles-alkalotolerant-fungus-trichothecium-sp-001892nas a2200265   4500008004100000022001400041245007000055210006900125260009500194300001400289490000600303520100600309653001701315653001001332653002601342653002401368653001801392100001701410700002701427700001501454700001701469700001701486700001901503856010401522       2008                        eng d  a1533-488000aStructure and microbial synthesis of sub-10 nm Bi2O3 nanocrystals0 aStructure and microbial synthesis of sub10 nm Bi2O3 nanocrystals  a25650 NORTH LEWIS WAY, STEVENSON RANCH, CA 91381-1439 USAbAMER SCIENTIFIC PUBLISHERScAUG  a3909-39130 v83 a<p>After the advent of novel chemical and microbial techniques, providing control over grain size and shape of the nanomaterials, several binary-oxide materials have been explored in size less than 10 nm for their tunable physical properties. Bi2O3 nanoparticles have also redrawn attention due to their excellent properties, mostly as optoelectronic material. Here, we report the room-temperature biosynthesis of Bi2O3 nanoparticles in a size range of 5-8 nm by extra-cellularly challenging the plant pathogenic fungus-Fusarium oxysporum with the bismuth nitrate as precursor. The as-synthesized particle-surfaces are inherently functionalized by a robust layer of proteins which provides them very good stability in the aqueous medium. Structural investigation using selected area electron diffraction, high resolution transmission electron microscopy and powder XRD shows that particles are almost perfectly single crystalline and primarily crystallize in alpha-phase with monoclinic structure.</p>10aBiosynthesis10afungi10aHigh Refractive Index10aHigh Resolution TEM10aNanoparticles1 aUddin, Imran1 aAdyanthaya, Suguna, D.1 aSyed, Asad1 aSelvaraj, K.1 aAhmad, Absar1 aPoddar, Pankaj  uhttps://library.ncl.res.in/content/structure-and-microbial-synthesis-sub-10-nm-bi2o3-nanocrystals-002203nas a2200205   4500008004100000022001400041245009300055210006900148260007300217300001000290490000700300520147600307653001701783653001101800653001801811653001301829100001501842700001701857856012301874       2012                        eng d  a0927-776500aExtracellular biosynthesis of platinum nanoparticles using the fungus fusarium oxysporum0 aExtracellular biosynthesis of platinum nanoparticles using the f  aPO BOX 211, 1000 AE AMSTERDAM, NETHERLANDSbELSEVIER SCIENCE BVcSEP  a27-310 v973 a<p>Nanoscience is a blooming field and promises a better future. In order to fabricate nanoparticles in an eco-friendly and inexpensive manner, significant efforts are being made to replace the chemical and physical methods currently being used with the biological methods. Chemical methods are toxic while the physical ones are very expensive. Biological methods, apart from being cost-effective, also provide protein capped nanoparticles which are thus very stable, have good dispersity and do not flocculate, and may find use in various applications. The present work emphasizes on platinum nanoparticles synthesis protocol which occurs at ambient conditions. The fungus Fusarium oxysporum when incubated with hexachloroplatinic acid (H2PtCl6) in ambient conditions reduces the precursor and leads to the formation of stable extracellular platinum nanoparticles. The biosynthesis of platinum nanoparticles was monitored by UV-visible spectroscopy and these nanoparticles were completely characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The nanoparticles are in the size range of 5-30 nm and are stabilized by proteins present in the solution. The reduction process is believed to occur enzymatically, thus creating the possibility of a rational, fungal-based method for the synthesis of nanoparticles over a wide range of chemical compositions. (C) 2012 Elsevier B.V. All rights reserved.</p>10aBiosynthesis10aFungus10aNanoparticles10aplatinum1 aSyed, Asad1 aAhmad, Absar  uhttps://library.ncl.res.in/content/extracellular-biosynthesis-platinum-nanoparticles-using-fungus-fusarium-oxysporum-001569nas a2200253   4500008004100000022001400041245008500055210006900140260007300209300001200282490000700294520071000301653001001011653001701021653001801038653001901056653002801075100002501103700001501128700001601143700002001159700001701179856011901196       2012                        eng d  a0167-577X00aIntracellular synthesis of gold nanoparticles using alga tetraselmis kochinensis0 aIntracellular synthesis of gold nanoparticles using alga tetrase  aPO BOX 211, 1000 AE AMSTERDAM, NETHERLANDSbELSEVIER SCIENCE BVcJUL  a116-1180 v793 a<p>The development of eco-friendly synthesis protocol for the synthesis of nanoscale materials of different compositions, shapes and sizes is an important area of research in the field of nanotechnology. In this paper, we report on the use of alga Tetraselmis kochinensis in the intracellular synthesis of gold nanoparticles of dimensions 5-35 nm. The particles are more concentrated upon the cell wall than on the cytoplasmic membrane, possibly due to reduction of the metal ions by enzymes present in the cell wall and cytoplasmic membrane. These intracellular nanoparticles may have applications in drug delivery, biomedical applications, catalysis, etc. (C) 2012 Elsevier B.V. All rights reserved.</p>10aAlgae10aBiosynthesis10aNanoparticles10ananotechnology10aTetraselmis kochinensis1 aSenapati, Satyajyoti1 aSyed, Asad1 aMoeez, Sana1 aKumar, Ashutosh1 aAhmad, Absar  uhttps://library.ncl.res.in/content/intracellular-synthesis-gold-nanoparticles-using-alga-tetraselmis-kochinensis-002302nas a2200241   4500008004100000022001400041245008900055210006900144260011100213300001200324490000600336520145700342653001701799653001101816653002301827653001501850653001101865653000801876100001301884700002101897700001701918856012501935       2013                        eng d  a1573-413700aExtra- and intracellular gold nanoparticles synthesis using live peanut callus cells0 aExtra and intracellular gold nanoparticles synthesis using live   aEXECUTIVE STE Y-2, PO BOX 7917, SAIF ZONE, 1200 BR SHARJAH, U ARAB EMIRATESbBENTHAM SCIENCE PUBL LTDcFEB  a107-1120 v93 a<p>An important challenge of considerable topical significance in nanotechnology is the development of eco-friendly experimental processes for the synthesis of nanomaterials in large quantities with variable sizes, shapes and chemical compositions. Green synthesis routes for the production of inorganic metal nanoparticles using whole cell of microorganisms and plant extracts are gaining tremendous popularity as these are non-toxic, cheap and occur at ambient conditions. The present work emphasizes on gold nanoparticles synthesis protocol using live plant callus cells. Peanut callus cells when incubated with HAuCl4 solution in ambient conditions reduced the precursor and lead to formation of well dispersed, water soluble extracellular and intracellular gold nanoparticles within 24 hours. The biosynthesis of gold nanoparticles was monitored by UV-visible spectroscopy (UV-Vis) and further characterized by X-ray diffraction analysis (XRD), Energy Dispersive Spectroscopy (EDS) and Selected Area Electron Diffraction (SAED). The particle size distribution shows that the average particle size is 50 nm for extra-and 31 nm for intracellular gold nanoparticles. The nanoparticles may be stabilized by proteins secreted by callus cells. The reduction process is believed to occur enzymatically, thus creating the possibility of a rational, plant cell-based method for the synthesis of nanoparticles over a wide range of chemical compositions.</p>10aBiosynthesis10acallus10agold nanoparticles10alive cells10aPeanut10aTEM1 aRaju, D.1 aMehta, Urmil, J.1 aAhmad, Absar  uhttps://library.ncl.res.in/content/extra-and-intracellular-gold-nanoparticles-synthesis-using-live-peanut-callus-cells-002033nas a2200217   4500008004100000022001400041245011900055210006900174260010600243300001000349490000800359520120700367653002701574653001701601653000901618653001101627653001801638100001501656700001701671856012701688       2013                        eng d  a1386-142500aExtracellular biosynthesis of CdTe quantum dots by the fungus fusarium oxysporum and their anti-bacterial activity0 aExtracellular biosynthesis of CdTe quantum dots by the fungus fu  aTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLANDbPERGAMON-ELSEVIER SCIENCE LTDcAPR  a41-470 v1063 a<p>The growing demand for semiconductor [quantum dots (Q-dots)] nanoparticles has fuelled significant research in developing strategies for their synthesis and characterization. They are extensively investigated by the chemical route; on the other hand, use of microbial sources for biosynthesis witnessed the highly stable, water dispersible nanoparticles formation. Here we report, for the first time, an efficient fungal-mediated synthesis of highly fluorescent CdTe quantum dots at ambient conditions by the fungus Fusarium oxysporum when reacted with a mixture of CdCl2 and TeCl4. Characterization of these biosynthesized nanoparticles was carried out by different techniques such as Ultraviolet-visible (UV-Vis) spectroscopy, Photoluminescence (PL), X-ray Diffraction (XRD), X-ray Photoelectron spectroscopy (XPS), Transmission Electron Microscopy (TEM) and Fourier Transformed Infrared Spectroscopy (FTIR) analysis. CdTe nanoparticles shows antibacterial activity against Gram positive and Gram negative bacteria. The fungal based fabrication provides an economical, green chemistry approach for production of highly fluorescent CdTe quantum dots. (C) 2013 Elsevier B.V. All rights reserved.</p>10aantibacterial activity10aBiosynthesis10aCdTe10aFungus10aNanoparticles1 aSyed, Asad1 aAhmad, Absar  uhttps://library.ncl.res.in/content/extracellular-biosynthesis-cdte-quantum-dots-fungus-fusarium-oxysporum-and-their-anti-002305nas a2200277   4500008004100000022001400041245009800055210006900153260011100222300001200333490000700345520133600352653001701688653001201705653001001717653001801727653001801745100002501763700001501788700001701803700001901820700002601839700001701865700001701882856012801899       2014                        eng d  a1573-413700aExtracellular biosynthesis of metal sulfide nanoparticles using the fungus fusarium oxysporum0 aExtracellular biosynthesis of metal sulfide nanoparticles using   aEXECUTIVE STE Y-2, PO BOX 7917, SAIF ZONE, 1200 BR SHARJAH, U ARAB EMIRATESbBENTHAM SCIENCE PUBL LTDcJUL  a588-5950 v103 a<p>The development of reliable, eco-friendly processes for the synthesis of nanomaterials is an important aspect of nanotechnology. One approach that shows immense potential is based on the biosynthesis of nanoparticles using microorganisms such as bacteria. In this report, we demonstrate the extracellular biosynthesis and complete characterization of metal sulfide (PbS, ZnS, MnS and NiS) nanoparticles using fungus, Fusarium oxysporum. We observed that the exposure of aqueous solution of 1 mM metal sulfate to fungus Fusarium oxysporum resulted in the formation of highly stable technologically important metal sulfide semiconductor nanoparticles. Fusarium oxysporum synthesizes lead sulfide and zinc sulfide nanoparticles of fractal type structure whereas manganese sulfide and nickel sulfide nanoparticles are of variable polydispersed morphology. The variable morphology may be due to the dissimilar interaction of metal sulfide nanoparticles with capping proteins secreted by the fungus in solution. The nanoparticles solution is found to be extremely stable with little evidence of aggregation even after a month of storage. The long term stability of the nanoparticles is due to the proteins secreted by fungus in the nanoparticle solution which bind to the surface of the nanoparticles and thus prevent aggregation.</p>10aBiosynthesis10aenzymes10afungi10ametal sulfide10aNanoparticles1 aSenapati, Satyajyoti1 aSyed, Asad1 aKhan, Shadab1 aPasricha, Renu1 aKhan, Mohammad, Islam1 aKumar, Rajiv1 aAhmad, Absar  uhttps://library.ncl.res.in/content/extracellular-biosynthesis-metal-sulfide-nanoparticles-using-fungus-fusarium-oxysporum-002331nas a2200301   4500008004100000022001400041245009800055210006900153260000900222300001000231490000700241520139200248653001701640653001701657653001701674653001401691653001601705653001701721100001501738700002601753700002101779700002701800700001901827700001701846700001801863700001701881856013101898       2022                        eng d  a1751-825300aAlpha Au2S nanoparticles: fungal-mediated synthesis, structural characterization and bioassay0 aAlpha Au2S nanoparticles fungalmediated synthesis structural cha  cJAN   a59-680 v153 aLuminescent nanoparticles synthesized via bio-based protocols that generate nanoparticles having different chemical compositions along with other functionalities (size and morphology) have received huge attention. We have focused our research on gold sulfide nanoparticles (Au2S NPs) and have biosynthesized these NPs using the fungus Humicola sp. The nanoparticles were characterized by Transmission Electron Microscopy, which showed spherical morphology of Au2S. UV-Visible-NIR spectrophotometry, luminescence spectrophotometry, Selected Area Electron Diffraction, Energy Dispersive Analysis of X-rays, and X-ray diffraction were performed. FTIR confirmed that the fungal metabolites including biomolecules secreted in the reaction medium are primarily responsible for nanoparticle synthesis and stabilization. The fungus reduced the precursor solution (HAuCl4 and Na2SO3) and at the same time capped them with secreted biomolecules. The anti-leishmanial activity of Au2S NPs was determined against L. donovani promastigote (Ag83 strain). Au2S NPs displayed less cytotoxicity towards both normal and cancer (Daudi, ZR-75-1) cell lines. Hemocompatibility was determined via hemolysis assays. This novel fungal-based system demonstrates an economical and environmentally benign process for biosynthesis of Au2S nanoparticles which may find application in bioimaging and labeling studies.10aBiosynthesis10aCytotoxicity10aGold sulfide10aHemolysis10ahumicola sp10apromastigote1 aSyed, Asad1 aSaedi, Marzouq, H. Al1 aBahkali, Ali, H.1 aElgorgan, Abdallah, M.1 aKharat, Mahesh1 aPai, Kalpana1 aPichtel, John1 aAhmad, Absar  uhttps://library.ncl.res.in/content/alpha-au2s-nanoparticles-fungal-mediated-synthesis-structural-characterization-and-bioassay