01819nas a2200217   4500008004100000022001400041245008100055210006900136260000800205520109100213653002601304653002101330653001801351653001201369653002301381100001901404700001701423700002701440700002401467856011001491       2021                        eng d  a1527-899900aPhosphorus ligands in hydroformylation and hydrogenation: a personal account0 aPhosphorus ligands in hydroformylation and hydrogenation a perso  cMAR3 a<p>Metal-catalyzed hydroformylation and hydrogenation heavily rely on ligands, among which phosphorous ligands play a pivotal role. This personal account presents a selection of three distinct classes of phosphorous ligands, namely, monodentate meta-substituted phosphinites, bis-phosphites, and P-chiral supramolecular phosphines, developed in our group. The synthesis of these ligands, isolation, characterization, and their performance in transition metal-catalyzed hydroformylation, isomerizing hydroformylation, and asymmetric hydrogenation of olefins is summarized. The state of the art development in iron-catalyzed hydroformylation of alkenes and our contributions to the field is discussed. Use of phosphines enabled iron-catalyzed hydroformylation of alkenes under mild conditions. Thus, this account demonstrates the central role of phosphorus ligands in industrially relevant transformations such as hydrogenation and hydroformylation. The seemingly matured field of ligand discovery still holds significant potential and will steer the field of homogeneous catalysis.</p>
10aHomogeneous catalysis10aHydroformylation10aHydrogenation10aOlefins10aPhosphorus ligands1 aTewari, Tanuja1 aKumar, Rohit1 aChandanshive, Amol, C.1 aChikkali, Samir, H.  uhttps://library.ncl.res.in/content/phosphorus-ligands-hydroformylation-and-hydrogenation-personal-account