02118nas a2200265   4500008004100000022001400041245015500055210006900210260000800279300001600287490000700303520118800310653002201498653001601520653003401536653002401570653000801594100002701602700001801629700001801647700001901665700002101684700002501705856012201730       2020                        eng d  a0360-319900aStructural, electrochemical and catalytic activity of Prussian blue analogues embedded with functionalized carbon for solid state battery applications0 aStructural electrochemical and catalytic activity of Prussian bl  cMAY  a15317-153260 v453 a<p>The nanoparticles of Mn-1.5[Cr(CN)(6)]center dot mH(2)O@Ni-1.5[Cr(CN)(6)]center dot nH(2)O core-shell prussian blue analogues (PBA) embedded with carbon additives (PBA-C) were synthesized and characterized as electrode material for solid state battery application. The impedance spectroscopy and cyclic voltametry were used to study the electrochemical properties by adding functionalized carbon in 1:1 proportion to improve the electrical performance. The value of room temperature electrical conductivity of core-shell PBA and core-shell nanoparticles mixed with vulcan carbon (PBA-C) are found to be 1.574 x 10(-3) and 1.92 x 10(-3) Scm(-1), respectively. Using Li2La3Zr2O12 (LZZO) electrolyte, single cell was fabricated with PBA-C material, and studied its charging-discharging cycles, which exhibits higher current density with stable performance for 400 cycles for time slots of 400 min. The study reveals that the PBA core-shell nanoparticles mixed with carbon (PBA-C) may be a potential candidate as an electrode material in the form of a single cell using LZZO electrolyte. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.</p>
10acyclic voltametry10aElectrolyte10aPrussian blue analogues (PBA)10aSolid state battery10aXPS1 aShaikh, Shabana, P. S.1 aBhatt, Pramod1 aYusuf, S., M.1 aBhange, S., N.1 aBansod, Sudhakar1 aAbdalla, Abdalla, M.  uhttps://library.ncl.res.in/content/structural-electrochemical-and-catalytic-activity-prussian-blue-analogues-embedded