01701nas a2200157   4500008004100000245016000041210006900201260000800270300001400278490000700292520105800299100001601357700001601373700001901389856013501408       2019                        eng d00aWhat news in the surface chemistry of bulk and supported vanadia based SCR‐catalysts: improvements in their resistance to poisoning and thermal sintering0 aWhat news in the surface chemistry of bulk and supported vanadia  cOCT  a1813-18280 v193 a<p>This paper reports a short review on the impact of poisoning effects and thermal aging on the reactivity of surface vanadate species on benchmark V2O5−WO3/TiO2 Selective‐Catalytic‐Reduction catalysts. A renewed interest of this SCR technology is related to its diversification notably as after‐treatment systems to treat the exhaust from Diesel engines with higher running temperature especially when SCR catalysts are coated on Diesel Particulates Filters. Particular attention is also paid to poisoning effects in conjunction with the progressive replacement of fossil fuels by bio‐fuels containing alkaline contaminants which drastically deactivate the catalyst through neutralization of strong acid sites. Most of the investigations show that better insight into the mechanisms of poisoning and aging processes is needed especially to understand the relative sensibility of various vanadate species. This could provide original guidelines to catalyst preparation and or the developments of more stable bulk systems as exemplified.</p>
1 aGranger, P.1 aSiaka, H.W.1 aUmbarkar, S.B.  uhttps://library.ncl.res.in/content/what-news-surface-chemistry-bulk-and-supported-vanadia-based-scr%E2%80%90catalysts-improvements