01133nas a2200145   4500008004100000245006300041210005900104260000800163300001400171490000600185520065600191100002600847700001900873856009500892       2018                        eng d00aDiastereoselective synthesis of (A±)- epi-subincanadine C0 aDiastereoselective synthesis of A± episubincanadine C  cMAY  a5308-53160 v33 aStarting from indolylmaleimide, concise and efficient total synthesis of (±)-epi-subincanadine C was described via stereoselective Wittig olefination, base-induced selective mono-prenylation, regioselective Grignard reaction, diastereoselective Pictet–Spengler cyclization, regioselective oxidative carbon–carbon double-bond cleavage, one-pot reductions, and intramolecular cyclization pathway. An attempted synthesis of (±)-subincanadine C via diastereoselective Grignard addition to the α,β-unsaturated γ-lactam or diastereoselective reduction of a carbon–carbon double bond also resulted in yet another route to (±)-epi-subincanadine C.1 aKalshetti, Manojkumar1 aArgade, N., P.  uhttps://library.ncl.res.in/content/diastereoselective-synthesis-%C2%B1-epi-subincanadine-c