02225nas a2200265   4500008004100000022001400041245013500055210006900190260008100259300001100340490000700351520123800358653002301596653001701619653002501636100002001661700001801681700002401699700002901723700002101752700002001773700002401793700001901817856012301836       2015                        eng d  a0953-898400aCombined experimental and theoretical study of the structural, electronic and vibrational properties of bulk and few-layer Td-WTe20 aCombined experimental and theoretical study of the structural el  aTEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLANDbIOP PUBLISHING LTDcJUL  a2854010 v273 a<p>The recent discovery of non-saturating giant positive magnetoresistance has aroused much interest in Td-WTe2. We have investigated structural, electronic and vibrational properties of bulk and few-layer Td-WTe2 experimentally and theoretically. Spin-orbit coupling is found to govern the semi-metallic character of Td-WTe2 and its structural link with the metallic 1 T form provides an understanding of its structural stability. There is a metal-to-insulator switch-over in the electrical conductivity and a change in the sign of the Seebeck coefficient around 373 K. Lattice vibrations of Td-WTe2 have been analyzed using first-principles calculations. Out of the 33 possible zone-center Raman active modes, five distinct Raman bands are observed around 112, 118, 134, 165 and 212 cm(-1) in bulk Td-WTe2. Based on symmetry analysis and calculated Raman tensors, we assign the intense bands at 165 cm(-1) and 212 cm(-1) to the A(1)' and A(1)'' modes, respectively. Most of the Raman bands stiffen with decreasing thickness, and the ratio of the integrated intensities of the A(1)'' to A(1)' bands decreases in the few-layer sample, while all the bands soften in both the bulk and few-layer samples with increasing temperature.</p>10aRaman spectroscopy10aTd-structure10atungsten ditelluride1 aJana, Manoj, K.1 aSingh, Anjali1 aLate, Dattatray, J.1 aRajamathi, Catherine, R.1 aBiswas, Kanishka1 aFelser, Claudia1 aWaghmare, Umesh, V.1 aRao, C., N. R.  uhttps://library.ncl.res.in/content/combined-experimental-and-theoretical-study-structural-electronic-and-vibrational-1