01151nas a2200169   4500008004100000245009700041210006900138260000800207300001600215490000700231520054600238100001700784700002000801700001500821700001900836856012600855       2017                        eng d00aTransition metal free catalytic hydroboration of aldehydes and aldimines by amidinato silane0 aTransition metal free catalytic hydroboration of aldehydes and a  cFEB  a2420 - 24240 v463 aThe transition metal free catalytic hydroboration of aldehydes and ketones is very limited and has not been reported with a well-defined silicon(iv) compound. Therefore, we chose to evaluate the previously reported silicon(iv) hydride [PhC(NtBu)2SiHCl2], (1) as a single component catalyst and found that it catalyzes the reductive hydroboration of a range of aldehydes with pinacolborane (HBpin) under ambient conditions. In addition, compound 1 can catalyze imine hydroboration. DFT calculation was carried out to understand the mechanism.1 aBisai, Milan1 aPahar, Sanjukta1 aDas, Tamal1 aSen, Sakya, S.  uhttps://library.ncl.res.in/content/transition-metal-free-catalytic-hydroboration-aldehydes-and-aldimines-amidinato-silane00817nas a2200157   4500008004100000245012400041210006900165260000800234490000700242520022400249100001700473700001500490700001700505700001900522856011800541       2018                        eng d00aEasily accessible lithium compound catalyzed mild and facile hydroboration and cyanosilylation of aldehydes and ketones0 aEasily accessible lithium compound catalyzed mild and facile hyd  cAPR0 v543 aSimple and readily accessible lithium compounds such as 2,6-ditertbutyl phenolate lithium (1a), 1,1' dilithioferrocene (1b) and nacnac lithium (1c) are found to be efficient single site catalysts for hydroboration of...1 aBisai, Milan1 aDas, Tamal1 aVanka, Kumar1 aSen, Sakya, S.  uhttps://library.ncl.res.in/content/easily-accessible-lithium-compound-catalyzed-mild-and-facile-hydroboration-and