01512nas a2200181   4500008004100000022001400041245014700055210006900202260011000271300001400381490000700395520072000402100002201122700002501144700001701169700001801186856012601204       2008                        eng d  a0959-942800aIn situ synthesis of Pt nanoparticles in SBA-15 by encapsulating in modified template micelles: size restricted growth within the mesochannels0 aIn situ synthesis of Pt nanoparticles in SBA15 by encapsulating   aTHOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLANDbROYAL SOC CHEMISTRYcFEB  a1765-17700 v183 a<p>A truly in situ and simple method is developed for nanoparticle incorporation within the mesochannels of SBA-15 involving dispersion of metal precursors in surfactant-modified polymer micelles. The diffusion of the precursor within the micellar structure is aided by interaction with the cationic head group of the surfactant leading to a unique method to facilitate the formation of highly disperse, uniform nanoparticles molded by the walls of the mesochannels. The nanoparticle incorporated mesoporous material has a highly enhanced surface area and adsorption capabilities in comparison to its parent materials without any pore blockage which makes this method ideal for the preparation of nanocatalysts.</p>1 aPrashar, Atul, K.1 aHodgkins, Robert, P.1 aKumar, Rajiv1 aDevi, Nandini  uhttps://library.ncl.res.in/content/situ-synthesis-pt-nanoparticles-sba-15-encapsulating-modified-template-micelles-size-001649nas a2200193   4500008004100000022001400041245009800055210006900153260007100222300001400293490000700307520090600314100002201220700002501242700002301267700002401290700001801314856012301332       2010                        eng d  a0897-475600aIn situ encapsulation of pt nanoarchitectures of varying morphologies in mesoporous compounds0 aIn situ encapsulation of pt nanoarchitectures of varying morphol  a1155 16TH ST, NW, WASHINGTON, DC 20036 USAbAMER CHEMICAL SOCcMAR  a1633-16390 v223 a<p>Nanoparticle morphology could be engineered and fine-tuned based on a novel in situ template method Different shapes of platinum nanoparticles were obtained from very low concentrations of precursors and could be isolated exclusively inside the mesochannels of SBA-15 This was achieved by dispersing a platinum precursor in surfactant modified polymer to different extents and using these composite materials as templates for the formation of mesoporous silica [PtCl(6)](2-) interacts with the cationic headgroup of the surfactant and facilitates the isolation of precursors within the composite template leading to the formation of nanoparticles molded by the walls of the mesochannels when calcined When this [PtCl(6)](2-)-surfactant-polymer micelle composite is aged for different duration, Pt nanoparticles of various morphologies like spheroids, nano rugby balls, and nanorods are obtained</p>1 aPrashar, Atul, K.1 aHodgkins, Robert, P.1 aChandran, Jima, N.1 aRajamohanan, P., R.1 aDevi, Nandini  uhttps://library.ncl.res.in/content/situ-encapsulation-pt-nanoarchitectures-varying-morphologies-mesoporous-compounds-001503nas a2200193   4500008004100000022001400041245011300055210006900168260007100237300001600308490000700324520074800331100002301079700002201102700002101124700001701145700002201162856012501184       2010                        eng d  a0888-588500aRu(II) phenanthroline complex as catalyst for chemoselective hydrogenation of nitro-aryls in a green process0 aRuII phenanthroline complex as catalyst for chemoselective hydro  a1155 16TH ST, NW, WASHINGTON, DC 20036 USAbAMER CHEMICAL SOCcDEC  a12180-121840 v493 a<p>Ru(II) Phenanthroline [Ru(II)(Phen)(n) where n = 1,2,3] complexes were used as highly chemoselective catalysts for hydrogenation of nitro aryls using molecular hydrogen in an aqueous media. Water, universal solvent, was used as a reaction mixture for hydrogenation of nitro-aryls to make the process green. The chemoselectivity in hydrogenation of substituted nitrobenzene to substituted aniline was obtained as high as &gt;99% at about complete conversion of substituted nitrobenzene. The parametric effects, including effect of solvent, effect of ligand, effect of metal to ligand ratio, effect of temperature and pressure, were studied in detail to obtain the best results. The Ru(Phen)(n) was characterized by FTIR, UV-vis, and XPS.</p>1 aDeshmukh, Amit, A.1 aPrashar, Atul, K.1 aKinage, Anil, K.1 aKumar, Rajiv1 aMeijboom, Reinout  uhttps://library.ncl.res.in/content/ruii-phenanthroline-complex-catalyst-chemoselective-hydrogenation-nitro-aryls-green-001780nas a2200229   4500008004100000022001400041245011700055210006900172260007900241300001400320490000700334520086600341653002701207653003801234653003101272653003101303100002101334700002201355700002001377700002601397856012701423       2011                        eng d  a1044-580300aGrowth of hydrothermally stable meso-porous silica structure interconnected around micro-porous zeolite crystals0 aGrowth of hydrothermally stable mesoporous silica structure inte  a360 PARK AVE SOUTH, NEW YORK, NY 10010-1710 USAbELSEVIER SCIENCE INCcDEC  a1166-11720 v623 a<p>The growth of hydrothermally stable ordered meso-porous silica with M41S type structure interconnected around zeolite crystals was achieved from seeds normally nucleating the crystallization of micro-porous zeolite. The solid state NMR and FT-IR showed species like Si(OSi)(3)OH and Si(OSi)(2)(OH)(2) (or Q(3) and Q(2) sites, respectively) are formed during first hydrothermal treatment with surfactant and NaOH. These species and surface silanol group of zeolite crystal condense to give meso-porous silica structure interconnected around zeolite crystal during re-crystallization at lower pH. Resulting meso-micro-porous hybrid material is found to be highly active, selective and stable in the synthesis of 2-(phenylamino) ethanol from aniline and ethylene carbonate compare to parent ZSM-5 and pure MCM-41. (C) 2011 Elsevier Inc. All rights reserved.</p>10aHydrothermal stability10aInterconnected meso-porous silica10aMeso-micro hybrid material10aSynthesis of amino alcohol1 aKinage, Anil, K.1 aPrashar, Atul, K.1 aBerlier, Gloria1 aChaturvedi, Rajiv, K.  uhttps://library.ncl.res.in/content/growth-hydrothermally-stable-meso-porous-silica-structure-interconnected-around-micro-001922nas a2200229   4500008004100000022001400041245014000055210006900195260007300264300001000337490000800347520104900355653001701404653002201421653002201443653002001465100002201485700001701507700002401524700001801548856012601566       2011                        eng d  a0926-860X00aIn situ encapsulation of Pt nanoparticles in mesoporous silica: synthesis, characterisation and effect of particle size on CO oxidation0 aIn situ encapsulation of Pt nanoparticles in mesoporous silica s  aPO BOX 211, 1000 AE AMSTERDAM, NETHERLANDSbELSEVIER SCIENCE BVcAUG  a91-970 v4033 a<p>Pt nanoparticles of narrow size distribution and average particle size of 4.4 nm are isolated exclusively inside SBA-12 mesoporous silica by a novel in situ method. The interaction of Pt precursor with surfactant-polymer composite micelle is followed by NMR and UV studies. The final Pt incorporated silica material is characterised by XRD, TEM and N(2) adsorption. The mesoporous nature of the silica is found to be intact after Pt incorporation without any pore blockage. CO oxidation activity of this material is compared with that of mesoporous silica incorporating different sizes of Pt viz., 1.8, 3.6 and 8 nm. Activation energies of CO oxidation for all these materials are calculated by a simple differential method based on first principles. A comparison of activation energies and single site yields reveals that these parameters are distinguishably less in catalyst containing 1.8 nm Pt nanoparticles but more or less same in catalysts containing 3.6, 4.4 and 8 nm Pt nanoparticles. (C) 2011 Elsevier B.V. All rights reserved.</p>10aCO oxidation10aIn situ synthesis10aMesoporous silica10aPt nanoparticle1 aPrashar, Atul, K.1 aMayadevi, S.1 aRajamohanan, P., R.1 aDevi, Nandini  uhttps://library.ncl.res.in/content/situ-encapsulation-pt-nanoparticles-mesoporous-silica-synthesis-characterisation-and-001696nas a2200253   4500008004100000022001400041245011300055210006900168260007300237300001000310490000700320520076400327653001001091653003101101653003301132653002101165653002201186653002101208653002801229100002201257700001701279700001801296856012801314       2012                        eng d  a1566-736700aEffect of particle size on selective hydrogenation of cinnamaldehyde by Pt encapsulated in mesoporous silica0 aEffect of particle size on selective hydrogenation of cinnamalde  aPO BOX 211, 1000 AE AMSTERDAM, NETHERLANDSbELSEVIER SCIENCE BVcNOV  a42-460 v283 a<p>Pt nanoparticles of various sizes, viz. 8. 4.9, 3.6 and 1.8 nm were encapsulated in 2D hexagonal mesoporous silica by in-situ synthesis as well as post synthetic modifications so that the final catalyst composition was &lt;= 1 wt.% Pt/SiO2. A kinetic analysis of the effect of particle size on selective hydrogenation of cinnamaldehyde was carried out on these catalysts. It was found that the materials, even at such low loading of Pt, were very active for the hydrogenation and selective for the desired product, cinnamyl alcohol. Among the different particle sizes, selectivity was found to be the highest on 8 nm particles. Kinetic analysis shows that the reaction follows a consecutive reaction pathway. (C) 2012 Elsevier B.V. All rights reserved.</p>10aalpha10abeta-Unsaturated aldehydes10aCinnamaldehyde hydrogenation10aKinetic analysis10aMesoporous silica10aPt nanoparticles10aSelective hydrogenation1 aPrashar, Atul, K.1 aMayadevi, S.1 aDevi, Nandini  uhttps://library.ncl.res.in/content/effect-particle-size-selective-hydrogenation-cinnamaldehyde-pt-encapsulated-mesoporous-0