02133nas a2200229   4500008004100000022001400041245012400055210006900179260000900248300001100257490000800268520131200276653002501588653002001613653003101633653002301664653001901687653002401706100001601730700002701746856013001773       2026                        eng d  a1010-603000aD-A-D based NIR and visible homodimeric squaraine dyes for dye-sensitized solar cells: Modulation of excitonic coupling0 aDAD based NIR and visible homodimeric squaraine dyes for dyesens  cAPR   a1168740 v4733 a<p>
	Dye-TiO2 interface plays a crucial role in the overall performance of dye-sensitized solar cells. Anchoring groups help to bind the dye on TiO2 and inject the electrons to the conduction band of TiO2. In this work, a series of homodimeric NIR squaraine dyes C6NIR, C10NIR, and visible squaraine dyes C6VIS, C10VIS are designed and synthesised. These dimeric dyes are covalently connected by decyl or hexyl units between the nonanchoring side of their monomeric unit. Optical spectroscopy in solution and on TiO2 surface indicates that the excitonic coupling between the dyes can be modulated. All the dimeric dyes showed better photovoltaic performance than their corresponding monomeric dyes. The dyes showed device performance SQ1 (1.28%) &lt; C6NIR (2.26%) &lt; C10NIR (2.79%) and AK2 (3.59%) &lt; C6VIS (4.34%) &lt; C10VIS (5.28%) respectively. The dimeric dyes showed better light harvesting efficiency and better passivation of the TiO2 surface. It helps to enhance the device's overall performance by improving the photocurrent and open circuit voltage. The decyl-linked dimeric dyes showed better performance among this set of dyes and C10NIR dyes showed V-oc of 614 mV, J(sc) of 7.08 mA/cm(2), and ff of 64.2%. and C10VIS showed V-oc of 724 mV, J(sc) of 10.74 mA/cm(2), and ff of 67.9%.</p>
10acharge recombination10aDye aggregation10aDye-sensitized solar cells10aDye-TiO2 interface10asquaraine dyes10asurface passivation1 aSiby, Jesna1 aNithyanandhan, Jayaraj  uhttps://library.ncl.res.in/content/d-d-based-nir-and-visible-homodimeric-squaraine-dyes-dye-sensitized-solar-cells-modulation