01357nas a2200181   4500008004100000022001400041245011100055210006900166260000800235300001400243490000700257520069200264100002100956700002700977700001801004700002501022856012801047       2024                        eng d  a0022-326300aHighly selective C-N and C-S dual functionalization of 1,3-dicarbonyl derivatives using TBHP as an oxidant0 aHighly selective CN and CS dual functionalization of 13dicarbony  cJUN  a9371-93800 v893 a<p>
	A direct electrosynthesis/photocatalyst-free, atom-economical, and efficient method for the selective synthesis of (E)-3-amino-2-thiocyanato-alpha,beta-unsaturated carbonyl compounds is described through a given protocol. The present approach features the use of inexpensive ammonium thiocyanate to achieve dual functionalization of 1,3-dicarbonyl compounds using TBHP as an oxidant, providing a rapid and practical route to the selective formation of both C-N and C-S bonds via a radical process. This method offers a broad substrate scope with excellent yield and allows for further exploration of the products to construct heterocyclic compounds and other functionalities.</p>
1 aBagad, Pooja, K.1 aDarole, Ratanamala, S.1 aKrishna, Rama1 aSenthilkumar, Beeran  uhttps://library.ncl.res.in/content/highly-selective-c-n-and-c-s-dual-functionalization-13-dicarbonyl-derivatives-using-tbhp