01756nas a2200217   4500008004100000022001400041245010600055210006900161260000900230300001600239490000600255520102400261653001601285653001101301653002301312653001201335100002801347700001901375700001901394856012501413       2023                        eng d  a2470-134300aMulticomponent solvate crystals of 3,5-dinitrobenzoic acid and acetamide and CSD analysis of solvates0 aMulticomponent solvate crystals of 35dinitrobenzoic acid and ace  cJUN   a24644-246530 v83 a<p>Twelve multicomponent solvate crystals (cocrystal solvates) of 3,5-dinitrobenzoic acid and acetamide were synthesized via slow evaporation method. All crystalline materials were characterized by single-crystal X-ray diffraction. All cocrystal solvates are isostructural, and crystal packing forms continuous channels where some solvent molecules are connected via weak intermolecular interactions with 3,5dinitrobenzoic acid and acetamide. All multicomponent solvate crystals encompass amide-amide dimer homo synthons and form R22 (8) motifs. Moreover, the phase purity of solvate crystals was analyzed by powder Xray diffraction. Further, most of the cocrystal solvates were analyzed by nuclear magnetic resonance and differential scanning calorimetry. Cambridge structural database analysis categorizes solvate propensity in single-crystal structures. The importance of hydrogen bond donor/ acceptor nature, size, and shape of solvents is also discussed in the context of crystallization and crystal packing.</p>
10aCo-Crystals10aDesign10aHost Guest Complex10asolvent1 aShaikh, Tabrez, Rafique1 aShelke, Nikita1 aTothadi, Srinu  uhttps://library.ncl.res.in/content/multicomponent-solvate-crystals-35-dinitrobenzoic-acid-and-acetamide-and-csd-analysis