01178nas a2200229 4500008004100000022001400041245013200055210006900187260000800256300001500264490000700279520035900286653002900645653002500674653002600699653001500725653001700740100002100757700002100778700002600799856012300825 2022 eng d a2193-580700aMetal-free access to hindered N-alkyl sulfoximines via in-situ generated Aza-oxyallyl cations from functionalized alkyl bromide0 aMetalfree access to hindered Nalkyl sulfoximines via insitu gene cJUL ae2022002100 v113 a

Herein, we report a catalyst-free and mild synthetic method for the construction of hindered N-alkyl sulfoximines derivative. A wide range of hindered di-alkyl sulfoximines can be readily obtained from the reaction of alpha-bromo-hydroxamates with a variety of sulfoximines, including diaryl, aryl-alkyl, di-alkyl and heteroaryl sulfoximines.

10aalpha-Bromo hydroxamates10aAza-oxyallyl cations10aDi-alkyl sulfoximines10ametal-free10aSulfoximines1 aMore, Satish, G.1 aMane, Kishor, D.1 aSuryavanshi, Gurunath uhttps://library.ncl.res.in/content/metal-free-access-hindered-n-alkyl-sulfoximines-situ-generated-aza-oxyallyl-cations