01462nas a2200193   4500008004100000022001400041245007300055210006900128260000800197490000700205520082600212653002501038653002101063653002201084653002101106653002101127100001701148856010301165       2022                        eng d  a1040-727800aPolyoxometalate clusters: inorganic ligands for functional materials0 aPolyoxometalate clusters inorganic ligands for functional materi  cSEP0 v333 a<p>
	Research in polyoxometalates (POMs) is a diverse growing field with variations in application. POMs are consisting of metal ion and oxide. Peripheral oxides of POM can share spare electron pairs to behave as ligands. This property of POM was utilized for constructing coordination polymers (CPs), synthesizing transitional metal substituted POM for catalysis, synthesizing and stabilizing nano-particles, etc. POM connected structures have provided an opportunity of heterogenization of some homogeneous POM catalyst. Furthermore, diamagnetic POM ligands have been suitable for stabilizing and isolating magnetic ions inside clusters. The scope of this review is to summarize the role of POMs as ligands to prepare POM based CPs, synthesize and stabilize metal nano-particles and isolate magnetic ion or unit.</p>
10aCoordination polymer10aInorganic ligand10amaterials science10apolyoxometalates10asynthesis design1 aDey, Chandan  uhttps://library.ncl.res.in/content/polyoxometalate-clusters-inorganic-ligands-functional-materials