01762nas a2200181   4500008004100000022001400041245014300055210006900198260000900267300001600276490000700292520106900299100002201368700001801390700002401408700001801432856013001450       2020                        eng d  a1463-907600aRole of B site ions in bifunctional oxygen electrocatalysis: a structure-property correlation study on doped Ca(2)Fe(2)O(5)brownmillerites0 aRole of B site ions in bifunctional oxygen electrocatalysis a st  cJUL   a15520-155270 v223 a<p>The role of B site doping with transition metals in brownmillerites, a perovskite related family of compounds, in bifunctional oxygen electrocatalysis,viz., simultaneous reduction and evolution reactions, is analysed. Ca2Fe1.9M0.1O5(M = Mn, Co, Ni, and Cu) is synthesised and structurally characterised by powder XRD and Rietveld refinement. Valence states of the surface B site ions are identified by X-ray photoelectron spectroscopy. Bifunctional oxygen electrochemistry is studied with the RDE and RRDE techniques and correlated with the structural and electronic parameters like oxygen non-stoichiometry and B site catalytic activity. Since the widely accepted electronic descriptors like e(g)filling may not be sufficient for explaining the bifunctional activity, B site electron donating capability as well as the extent of oxygen vacancies enhancing O(2)adsorption is also considered. Such structural parameters are also found to influence both the ORR and OER and based on this, Ni doping is proposed as advantageous for the bifunctional activity.</p>
1 aThundiyil, Shibin1 aVinod, C., P.1 aKurungot, Sreekumar1 aDevi, Nandini  uhttps://library.ncl.res.in/content/role-b-site-ions-bifunctional-oxygen-electrocatalysis-structure-property-correlation-study