01317nas a2200169   4500008004100000022001400041245007000055210006800125260000800193300001600201490000600217520077500223100002000998700001701018700001901035856009301054       2020                        eng d  a2470-134300aCyanosilylation by compounds with main-group elements: an odyssey0 aCyanosilylation by compounds with maingroup elements an odyssey  cOCT  a25477-254840 v53 a<p>The past few decades have seen remarkable headways in the structural and reaction chemistry of compounds with heavier main-group elements. In recent years, there is an ongoing effort to derive catalytic chemistry involving main-group compounds, driven by their lower costs and higher terrestrial abundances. Here, a survey on the state-of-the-art in the development of cyanosilylation methodology by compounds with heavier main-group elements has been given. Once dominated by transition metals, the field has matured to embrace the majority of the main-group elements including aluminum, silicon, and calcium. Of particular focus will be how the mechanism of cyanosilylation involving compounds with main-group elements differs from those of transition metals.</p>
1 aPahar, Sanjukta1 aKundu, Gargi1 aSen, Sakya, S.  uhttps://library.ncl.res.in/content/cyanosilylation-compounds-main-group-elements-odyssey