01844nas a2200241   4500008004100000022001400041245017000055210006900225260000800294300001100302490000800313520098400321653002201305653001801327653001301345653002201358653001901380653000801399100002101407700002101428700002101449856013201470       2020                        eng d  a0021-961400aExperimental analysis of vapour-liquid phase equilibria for binary systems of diethyl carbonate with methyl, ethyl, isopropyl, n-butyl and isoamyl acetates at 95 kPa0 aExperimental analysis of vapourliquid phase equilibria for binar  cNOV  a1061890 v1503 a<p>Experimental analysis of vapour-liquid phase equilibrium (VLE) for five binary pairs of diethyl carbonate (DEC) with methyl acetate, ethyl acetate, isopropyl acetate, n-butyl acetate and isoamyl acetate was carried out in this study. VLE data were generated experimentally at local atmospheric pressure of 95 kPa in a glass dynamic recirculation still. Reliability of data was checked with the thermodynamic consistency tests by Van Ness, infinite dilution, pure component and mean absolute deviation test. Experimental data was found to be thermodynamically consistent with all tests and data was regressed with Wilson, NRTL and UNIQUAC activity coefficient models to determine binary interaction parameters. Binary pair of DEC with n-butyl acetate has shown azeotropic behaviour with minimum boiling azeotrope and a close boiling behaviour through-out the composition range. No azeotropic behaviour was observed for the rest of the binary pairs. (c) 2020 Elsevier Ltd.</p>
10aDiethyl carbonate10aethyl acetate10aIsobaric10aIsopropyl acetate10amethyl acetate10aVLE1 aBhoi, Bharat, R.1 aMali, Nilesh, A.1 aJoshi, Sunil, S.  uhttps://library.ncl.res.in/content/experimental-analysis-vapour-liquid-phase-equilibria-binary-systems-diethyl-carbonate-methyl