01276nas a2200169   4500008004100000022001400041245017700055210006900232260000900301300001600310490000700326520059500333100002600928700002300954700002600977856010301003       2020                        eng d  a0022-326300aRadical rearrangement of aryl/alkylidene malononitriles via aza michael addition/decynoformylation/addition sequence: an access to alpha-aminonitriles and alpha-aminoamides0 aRadical rearrangement of arylalkylidene malononitriles via aza m  cDEC   a14858-148650 v853 a<p>An efficient, safe, and environmentally friendly tertiary butyl hydrogen peroxide (TBHP)-mediated rearrangement of aryl/alkylidene malononitrile with anilines has been developed with in situ generation of HCN as the cyanide source for the synthesis of substituted alpha-aminonitriles and alpha-aminoamide. A diverse set of alpha-aminonitriles and alpha-aminoamides was efficiently synthesized in good to excellent yields. This method features a broad substrate scope and good functional group tolerance, and the in situ-generated HCN bypasses the use of an external cyanide source.</p>
1 aBhoite, Shubhangi, P.1 aBansodes, Ajay, H.1 aSuryavanshi, Gurunath  uhttps://library.ncl.res.in/content/radical-rearrangement-arylalkylidene-malononitriles-aza-michael