00994nas a2200169 4500008004100000022001400041245010700055210006900162260000800231300001400239490000700253520038200260100001900642700001600661700001800677856012900695 2018 eng d a1477-052000aOrganocatalyst bound -aminoalkyl radical intermediate for controlled aerobic oxidation of iminium ions0 aOrganocatalyst bound aminoalkyl radical intermediate for control cJUL a5081-50850 v163 a

A catalyst bound -aminoalkyl radical intermediate from iminium is developed to control its formation and reactivity with aerobic oxygen. The influence of the catalyst was demonstrated via the ease of radical intermediate formation and its subsequent reactivity, including the first catalyst-controlled enantioselective aerobic oxidation with a chiral phosphite catalyst.

1 aMotaleb, Abdul1 aBera, Asish1 aMaity, Pradip uhttps://library.ncl.res.in/content/organocatalyst-bound-aminoalkyl-radical-intermediate-controlled-aerobic-oxidation-iminium