01288nas a2200169   4500008004100000245008600041210006900127260000800196300002700204490000800231520067600239100002200915700002400937700002100961700003400982856010201016       2017                        eng d00aDetermination of onset temperature from the entropy for fragile to strong liquids0 aDetermination of onset temperature from the entropy for fragile   cJUL  aArticle Number: 0245040 v1473 a<p>In this paper, we establish a connection between the onset temperature of glassy dynamics with the change in the entropy for a wide range of model systems. We identify the crossing temperature of pair and excess entropies as the onset temperature. Below the onset temperature, the residual multiparticle entropy, the difference between excess and pair entropies, becomes positive. The positive entropy can be viewed as equivalent to the larger phase space exploration of the system. The new method of onset temperature prediction from entropy is less ambiguous, as it does not depend on any fitting parameter like the existing methods. Published by AIP Publishing.</p>1 aBanerjee, Atreyee1 aNandi, Manoj, Kumar1 aSastry, Srikanth1 aBhattacharyya, Sarika, Maitra  uhttps://library.ncl.res.in/content/determination-onset-temperature-entropy-fragile-strong-liquids