01310nas a2200145   4500008004100000245011500041210006900156260000800225300001400233490000700247520074500254100002000999700003101019856011401050       2006                        eng d00aDerivatisation and transition metal chemistry of a new monophosphinite ligand: 2-(diphenylphosphinoxy)naphthyl0 aDerivatisation and transition metal chemistry of a new monophosp  cJUN  a1390-13940 v453 a<p>Reaction of monophosphinite ligand, 2-(diphenylphosphinoxy) naphthyl, C10H7PPh2 (1) with elemental sulphur or selenium gives the corresponding sulphide C10H7OP(S)Ph2 (2) or selenide C10H7OP(Se)ph2 (3) derivatives. Reaction of 1 with [CpRu(PPh3)2Cl] gives monosubstituted complex, [CpRu(C10H7OPPh2)(PPh3)C1] (4) as well as the disubstituted complex. [CpRu(C10H7PPh2)2Cl] (5) depending upon the reaction conditions. Treatment of 1 with [Rh(CO)2Cl]2 affords a trans-complex, [Rh(CO)(C10H7PPh2Cl] (6). Reaction of 1 with [Pd(COD)Cl2] results in the formation of an unexpected chlorobridged dipalladium complex: [Pd (PPh2O)( PPh2OH)(μ-Cl)]2 (7), whereas similar reaction with [pt(COD)Cl2] gives cis-[Pt(C10H7PPh2)2Cl2] (8) in good yield.</p>1 aPunji, Benudhar1 aBalakrishna, Maravanji, S.  uhttps://library.ncl.res.in/content/derivatisation-and-transition-metal-chemistry-new-monophosphinite-ligand-2