01300nas a2200169   4500008004100000245008800041210006900129260000800198300001400206490000700220520069600227100002000923700002000943700002200963700003100985856011401016       2009                        eng d00aCopper (I) complexes of a thioether-functionalized short-bite aminobis(phosphonite)0 aCopper I complexes of a thioetherfunctionalized shortbite aminob  cNOV  a101–1060 v283 a<p>Copper(I) complexes of short-bite aminobis(phosphonite), PhN{P(–OC10H6(μ-S)C10H6O–)}2 (1) have been synthesized. Reactions of 1 with an excess of CuX (X = Cl, Br, and I) afforded the ligand-bridged binuclear complexes, [PhN(PR-κP)2{Cu(μ-X)(MeCN)}2] (2, X = Cl; 3, X = Br; 4, X = I; R = –OC10H6(μ-S)C10H6O–), whereas treatment with 0.5 equiv. of [Cu(MeCN)4]PF6 produces the mononuclear bischelated cationic complex, [{PhN(PR-κP)2}2Cu](PF6) (5). Single crystal X-ray structures of complexes 3 and 4 are reported. Complex 3 shows strong π–π stacking interactions between the naphthyl moieties, whereas complex 4 shows ligand-supported Cu⋯Cu metallophilic interactions.</p>1 aPunji, Benudhar1 aMague, Joel, T.1 aMobin, Shaikh, M.1 aBalakrishna, Maravanji, S.  uhttps://library.ncl.res.in/content/copper-i-complexes-thioether-functionalized-short-bite-aminobisphosphonite