01387nas a2200169   4500008004100000245010600041210007000147260000800217300001400225490000800239520075000247100003100997700001701028700002001045700002001065856013201085       2010                        eng d00aLarge-bite bisphosphite, 1,3-C6H4{OPOC10H6(μ-S)C10H6O}2: synthesis, copper(I), and gold(I) complexes0 aLargebite bisphosphite 13C6H4 OPOC10H6μSC10H6O 2 synthesis coppe  cNOV  a981–9860 v6953 a<p>Large-bite bisphosphite ligand 1,3-C6H4{OPOC10H6(μ-S)C10H6O}2 (3), is obtained by reacting chlorophosphonite {OC10H6(μ-S)C10H6O}PCl (2) with resorcinol in the presence of triethylamine. Treatment of 3 with CuCl in 1:1 molar ratio produces a 1D-coordination polymer [CuCl{(–OC10H6(μ-S)C10H6O–)P(–OC6H4O–)P(–OC10H6(μ-S)C10H6O–)}-κP,κP]∞ (4) in good yield. Similar reaction of 3 with two equivalents of AuCl(SMe2) affords a dinuclear complex, [Au2Cl2{(–OC10H6(μ-S)C10H6O–)P(–OC6H4O–)P(–OC10H6(μ-S)C10H6O–)}-κP,κP] (5). Single crystal X-ray structures of the ligand 3 and the complexes 4 and 5 are reported. The gold complex 5 shows dimeric structure supported by strong Au···Au aurophilic interactions.</p>1 aBalakrishna, Maravanji, S.1 aKumar, Pawan1 aPunji, Benudhar1 aMague, Joel, T.  uhttps://library.ncl.res.in/content/large-bite-bisphosphite-13-c6h4opoc10h6%CE%BC-sc10h6o2-synthesis-copperi-and-goldi-complexes