01865nas a2200193   4500008004100000245012300041210006900164260000800233300001400241490000700255520115700262100001801419700002601437700002101463700002401484700002301508700001701531856012301548       2012                        eng d00aAlternative approach: a highly selective dual responding fluoride sensor having active methylene group as binding site0 aAlternative approach a highly selective dual responding fluoride  cJAN  a2263-22710 v103 a<p>A newly designed phosphonium derivative (L) having active methylene functionality, shows unusual preference towards F− over all other anions. The binding process through C–H⋯F− hydrogen bond formation was probed by monitoring the changes in either electronic or luminescence spectra. Changes in both cases are significant enough to allow visual detection. The loss of molecular flexibility of L on forming L·F− effectively interrupts the non-radiative deactivation pathway and accounts for the observed switch on fluorescence response. The results of the time-resolved emission studies for L and L·F− using a time-correlated single photon counting technique further corroborate this presumption. The excellent preference of L towards F− is attributed to an efficient hydrogen bonding interaction between the strongly polarized methylene protons and F−, which delineates the subtle difference in the affinity among other competing anionic analytes like CN−, H2PO4−, CH3CO2−, etc. The relative affinities of various anions and the preferential binding of F− to reagent L are also rationalized using computational studies.</p>1 aDas, Priyadip1 aKesharwani, Manoj, K.1 aMandal, Amal, K.1 aSuresh, Eringathodi1 aGanguly, Bishwajit1 aDas, Amitava  uhttps://library.ncl.res.in/content/alternative-approach-highly-selective-dual-responding-fluoride-sensor-having-active