01386nas a2200205   4500008004100000022001400041245011200055210006900167260009000236300001000326490000600336520055300342100002000895700002400915700002900939700002400968700003200992700003001024856012601054       2016                        eng d  a2045-232200a1000-fold enhancement in proton conductivity of a MOF using post-synthetically anchored proton transporters0 a1000fold enhancement in proton conductivity of a MOF using posts  aMACMILLAN BUILDING, 4 CRINAN ST, LONDON N1 9XW, ENGLANDbNATURE PUBLISHING GROUPcAUG  a324890 v63 a<p>Pyridinol, a coordinating zwitter-ionic species serves as stoichiometrically loadable and non-leachable proton carrier. The partial replacement of the pyridinol by stronger hydrogen bonding, coordinating guest, ethylene glycol (EG), offers 1000-fold enhancement in conductivity (10(-6) to 10(-3) Scm(-1)) with record low activation energy (0.11 eV). Atomic modeling coupled with C-13-SSNMR provides insights into the potential proton conduction pathway functionalized with post-synthetically anchored dynamic proton transporting EG moieties.</p>1 aShalini, Sorout1 aDhavale, Vishal, M.1 aEldho, Kavalakal, Mathai1 aKurungot, Sreekumar1 aAjithkumar, Thalasseril, G.1 aVaidhyanathan, Ramanathan  uhttps://library.ncl.res.in/content/1000-fold-enhancement-proton-conductivity-mof-using-post-synthetically-anchored-proton