01254nas a2200253   4500008004100000022001400041245007900055210006900134260010600203300001200309490000700321520034100328653001500669653002000684653002800704653003100732653001800763653002300781100001900804700002100823700002800844700002400872856010400896       2007                        eng d  a0040-403900aTotal synthesis of pachastrissamine (jaspine B) enantiomers from D-glucose0 aTotal synthesis of pachastrissamine jaspine B enantiomers from D  aTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLANDbPERGAMON-ELSEVIER SCIENCE LTDcJAN  a265-2680 v483 a<p>Synthesis of both enantiomers of pachastrissamine is described from a common chiral template. The stereoselective construction of the central tetrahydrofuran units was based on the pseudodesymmetrization of a pentodialdo-1,4-furanose derivative taking advantage of the latent symmetry present. (c) 2006 Published by Elsevier Ltd.</p>10a4-furanose10achiron approach10aOhira-Bestmann reaction10apachastrissamine/jaspine B10apentodialdo-110aring isomerization1 aRamana, C., V.1 aGiri, Awadut, G.1 aSuryawanshi, Sharad, B.1 aGonnade, Rajesh, G.  uhttps://library.ncl.res.in/content/total-synthesis-pachastrissamine-jaspine-b-enantiomers-d-glucose