01795nas a2200277   4500008004100000022001400041245011700055210006900172260006900241300001400310490000800324520078600332653002101118653001401139653001501153653003001168653004301198653002201241100002001263700001901283700002601302700002301328700002601351700001501377856012501392       2005                        eng d  a0022-328X00aSynthesis, structure, electrochemistry and ROMP-activity of new ferrocenyl analog of Grubbs' metathesis catalyst0 aSynthesis structure electrochemistry and ROMPactivity of new fer  aPO BOX 564, 1001 LAUSANNE, SWITZERLANDbELSEVIER SCIENCE SAcFEB  a1018-10270 v6903 a<p>Treatment of [(PCy3)(2)Cl2Ru=CH-Ph] (1) with vinylferrocene 1 and 1-ferrocenyl-1,3-butadiene 2 yielded solid products. These new complexes were characterized by H-1 NMR, P-31 NMR and C-13 NMR spectroscopy. X-ray crystal structures of both the complexes have been solved. The crystal structure of II confirmed the assigned structure and revealed existence of two sets of intermolecular C-H-Cl(M) type interactions, viz. (Ru)Cl-H-C(ferrocene) and (Ru)Cl-H-CHCl2. The air-stable, dark solid II is all efficient catalyst for ring-opening metathesis polymerization (ROMP) of cyclopentene, norbornene and cycloocta-1,5-diene. Electrochemical behavior of the complexes clearly reflects electronic communication between two metal centers. (C) 2004 Elsevier B.V. All rights reserved.</p>10aElectrochemistry10aferrocene10aMetathesis10anon-covalent interactions10aring-opening metathesis polymerization10aruthenium carbene1 aMaishal, T., K.1 aMondal, Biplab1 aPuranik, Vedavati, G.1 aWadgaonkar, P., P.1 aLahiri, Goutam, Kumar1 aSarkar, A.  uhttps://library.ncl.res.in/content/synthesis-structure-electrochemistry-and-romp-activity-new-ferrocenyl-analog-grubbs-1