02110nas a2200253   4500008004100000022001400041245010600055210006900161260006800230300001400298490000700312520123700319653001701556653001401573653001501587653002001602653001001622653001401632100001901646700002501665700002401690700001901714856012301733       2005                        eng d  a0887-626600aPoly(acrylonitrile) ultrafiltration membranes. II. membrane morphology and permeation characteristics0 aPolyacrylonitrile ultrafiltration membranes II membrane morpholo  a111 RIVER ST, HOBOKEN, NJ 07030 USAbJOHN WILEY & SONS INCcAUG  a2074-20850 v433 a<p>The rheology and phase-boundary characteristics of various solutions comprising three polyacrylonitrile (PAN) grades dissolved in solutions of N,N-dimethylformamide + salt (LiCl, ZnCl2, or AICl(3)) additives were correlated with the resulting membrane morphology as determined by microscopy and permeability measurements. The phase separation characteristics of the dope solution were not markedly affected by the PAN molecular weight (MW); however, they were affected by the salt additive. For higher MW grades, the effect of salt addition can also be masked by the increased self-association tendency of the polymer chains. PAN-B and -C membranes were clearly less asymmetric in structure than the lower MW PAN-Abased membranes. This is attributed to the higher viscosity/lower diffusivity of the PAN-13 and -C solutions, which results in slower solvent-nonsolvent exchange during the phase inversion process. Two factors reduce the incidence of surface defects (increased bubble points): (a) higher solution viscosity dampens surface perturbations during phase inversion, and (b) phase inversion pathways resulting in more homogenous morphology lead to membranes with higher bubble points. (c) 2005 Wiley Periodicals, Inc.</p>10abubble point10amembranes10aMorphology10aphase inversion10asalts10aviscosity1 aPhadke, M., A.1 aKulkarni, Sudhir, S.1 aKarode, Sandeep, K.1 aMusale, D., A.  uhttps://library.ncl.res.in/content/polyacrylonitrile-ultrafiltration-membranes-ii-membrane-morphology-and-permeation-0