02227nas a2200241   4500008004100000022001400041245005500055210005200110260006900162300001200231490000700243520144600250653003001696653003701726653001801763653002101781653001501802100002001817700001901837700002201856700002001878856008701898       2006                        eng d  a0254-058400aSynthesis of star shaped Ba1-xSrTiO3 (BST) powders0 aSynthesis of star shaped Ba1xSrTiO3 BST powders  aPO BOX 564, 1001 LAUSANNE, SWITZERLANDbELSEVIER SCIENCE SAcJUN  a295-3000 v973 a<p>Uniform star shaped strontium substituted barium titanyl oxalate Ba1-xSrxTiO(C2O4)(2) (BSTO)/strontium substituted barium titanate, Ba1-xSrxTiO3 (BST) powders were prepared via a simple chemical co-precipitation route with x = 0.15, 0.20, and 0.25. The process involved an addition of 0.1 M solution of titanium tetrabutoxide (BTM) in isopropanol (IPA) to 0.1 M oxalic acid in IPA containing 0.2 M of H2O to produce titanyl oxalate precipitate which was further reacted with 0.1 M solution of ammonium oxalate to obtain 0.1 M clear homogeneous solution of ammonium titanyl oxalate (ATO) with pH 4.25 containing titanium in the form of soluble anionic oxalate species [TiO(C2O4)(2)(2-)]. Stoichiometric quantities of barium hydroxide and strontium nitrate were dissolved in distilled water and its pH was adjusted nearly equal to that of ATO (similar to 4.15) by drop wise addition of dilute HNO3 solution 1:10 (v/v). The addition of this mixed cation precursor solution to ATO solution resulted in precipitation of strontium substituted barium titanyl oxalate (BSTO) having star shaped morphology. The calcination of BSTO precursors at 730 degrees C for 4 h in air produced cubic BST powders (a(o) similar to 4.001, 3.996 and 3.991 angstrom for x = 0. 15, 0.20, 0.25, respectively) having star shaped morphology. SEM, XRD and IFTIR techniques were used to characterize the BSTO/BST powders. (c) 2005 Elsevier B.V. All rights reserved.</p>10abarium-strontium titanate10abarium-strontium titanyl oxalate10acapping agent10aCo-precipitation10aMorphology1 aKhollam, Y., B.1 aPotdar, H., S.1 aDeshpande, S., B.1 aGaikwad, A., B.  uhttps://library.ncl.res.in/content/synthesis-star-shaped-ba1-xsrtio3-bst-powders-1