02258nas a2200253   4500008004100000022001400041245008700055210006900142260010600211300001400317490000700331520135200338653001801690653001201708653002301720653001901743653002101762100002201783700001701805700002301822700001801845700002101863856012001884       2009                        eng d  a0013-468600aConducting polyaniline-nano-TiO2 composites for smart corrosion resistant coatings0 aConducting polyanilinenanoTiO2 composites for smart corrosion re  aTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLANDbPERGAMON-ELSEVIER SCIENCE LTDcJAN  a1249-12540 v543 a<p>Coatings prepared from polyaniline-nano-TiO2 particles synthesized by in situ polymerization were found to exhibit excellent corrosion resistance much superior to polyaniline (PANI) in aggressive environments. The corrosion Studies were carried out on steel plates coated with these formulations containing 10 wt% polyaniline prepared with different concentrations of nano-TiO2. The electrochemical impedance spectroscopy was studied at periodic intervals during exposure to hot saline (65 degrees C) conditions for prolonged durations over a period of 90 h. The open circuit potential (OCP) was found to shift with time from -0.38 V SCE to more anodic side (-0.2 V SCE) much above that of bare steel (-0.5 VSCE). The presence of nano-TiO2 was found to be vital in the prevention of corrosion and the shift of OCP to anodic side. From these data, one could envisage more than 100 times improvement in the corrosion resistance especially for polyaniline prepared with 4.18 wt% nano-TiO2. The exceptional improvement of performance of these coatings has been associated with the increase in barrier to diffusion, prevention of charge transport by the nanosize TiO2, redox properties of polyaniline as well as very large surface area available for the liberation of dopant due to nano-size additive. (C) 2008 Elsevier Ltd. All rights reserved.</p>10aAnticorrosion10aCoating10aconducting polymer10aNano-composite10aTitanium dioxide1 aRadhakrishnan, S.1 aSiju, C., R.1 aMahanta, Debajyoti1 aPatil, Satish1 aMadras, Giridhar  uhttps://library.ncl.res.in/content/conducting-polyaniline-nano-tio2-composites-smart-corrosion-resistant-coatings-0