01644nas a2200193   4500008004100000022001400041245011800055210006900173260007100242300001400313490000700327520087900334100001701213700002001230700002501250700002901275700001801304856012801322       2009                        eng d  a0888-588500aMass transfer and solubility of CO and H-2 in ionic liquid. case of [Bmim][PF6] with gas-inducing stirrer reactor0 aMass transfer and solubility of CO and H2 in ionic liquid case o  a1155 16TH ST, NW, WASHINGTON, DC 20036 USAbAMER CHEMICAL SOCcAPR  a4075-40820 v483 a<p>Since the past decade, ionic liquids have gained significant importance as alternative solvents for catalysis applications. Many of the reactions evaluated in ionic liquids employ gases as substrates, and therefore it is important to know their solubility and mass transfer characteristics. This work reports for the first time both the solubility and volumetric gas-liquid mass transfer coefficient k(La) for hydrogen and carbon monoxide in 1-n-butyl-3-methylimidazolium hexafluorophosphate ([Bmim][PF6]) at three temperatures (293, 323, and 373 K) in relevance to hydroformylation reaction. The experimental data on the volumetric gas-liquid mass transfer coefficient are described by a dimensionless correlation for the bench-scale stirred tanks with gas-inducing impeller. k(La) values have also been evaluated for different [Bmim][PF6]-decane emulsions at 373 K.</p>1 aSharma, Amit1 aJulcour, Carine1 aKelkar, Ashutosh, A.1 aDeshpande, Raj, Madhukar1 aDelmas, Henri  uhttps://library.ncl.res.in/content/mass-transfer-and-solubility-co-and-h-2-ionic-liquid-case-bmimpf6-gas-inducing-stirrer-0