01777nas a2200217   4500008004100000022001400041245006800055210006800123260007300191300001200264490000700276520102000283653002001303653001801323653002301341653002201364653002701386100002101413700002601434856009901460       2010                        eng d  a0378-382000aThermodynamic analysis of dry autothermal reforming of glycerol0 aThermodynamic analysis of dry autothermal reforming of glycerol  aPO BOX 211, 1000 AE AMSTERDAM, NETHERLANDSbELSEVIER SCIENCE BVcMAY  a520-5300 v913 a<p>{Dry autothermal reforming of glycerol uses a combination of dry (CO(2)) reforming and partial oxidation reactions to produce syngas rich product stream. Thermodynamic equilibrium data for dry autothermal reforming of glycerol was generated for temperature range 600-1000 K . 1 bar pressure, OCGR [feed O(2)/C (C of glycerol only) ratio] 0.1 to 0.5 and CGR [feed CO(2)/glycerol ratio] 1 to 5 and analyzed. The objective of the paper is to identify the thermodynamic domain of the process operation, study the variation of product distribution pattern and describe the optimum conditions to maximize yield of the desired product and minimize the undesired product formation. Higher OCGR and higher CGR yielded a syngas ratio (similar to 1), with lower carbon and methane formation, while lower CGR and lower OCGR yielded good hydrogen and total hydrogen, with low water and CO2 production. The best thermoneutral condition for DATR of glycerol operation was seen at a temperature of 926.31 K at 1 bar pressure</p>10aCO(2) reforming10aDry reforming10aGlycerol reforming10aSyngas production10aThermodynamic modeling1 aKale, Ganesh, R.1 aKulkarni, Bhaskar, D.  uhttps://library.ncl.res.in/content/thermodynamic-analysis-dry-autothermal-reforming-glycerol-0