01507nas a2200181   4500008004100000022001400041245012300055210006900178260007100247300001400318490000700332520078300339100002101122700001401143700001901157700002001176856012901196       2010                        eng d  a1528-748300aStructural, magnetic, and gas adsorption study of a two-dimensional tetrazole-pyrimidine based metal-organic framework0 aStructural magnetic and gas adsorption study of a twodimensional  a1155 16TH ST, NW, WASHINGTON, DC 20036 USAbAMER CHEMICAL SOCcJUN  a2475-24780 v103 a<p>A new two-dimensional (2D) metal-organic framework, Cu-TP-1, has been synthesized under solvothermal conditions (DMF) from the transition metal cation Cu(II) and 2-tetrazole pyrimidine (C5H5N6, H-TP). The structure has been determined by single crystal X-ray crystallography which shows a (6,3) honeycomb 2D net with perpendicular one-dimensional channels. Permanent porosity of Cu-TP-1 has been determined by the nitrogen adsorption isotherm. Cu-TP-1 show interesting H-2 and CO2 uptake. CO2 uptake of Cu-TP-1 (at 298 K, 1 atm pressure) is seen to be comparable to the recently reported ZIF-95 which outperforms ZIF-100 and BPL carbon. The magnetic properties show an antiferromagnetically coupled Cu ... Cu interaction down to 8 K with a Weiss temperature around 108 K.</p>1 aPachfule, Pradip1 aDas, Raja1 aPoddar, Pankaj1 aBanerjee, Rahul  uhttps://library.ncl.res.in/content/structural-magnetic-and-gas-adsorption-study-two-dimensional-tetrazole-pyrimidine-based-0