01537nas a2200193   4500008004100000022001400041245014600055210006900201260007100270300001600341490000700357520072900364100001701093700002901110700002901139700002501168700001801193856013201211       2010                        eng d  a0888-588500aHydroformylation of 1-octene using [Bmim][PF6]-decane biphasic media and rhodium complex catalyst: thermodynamic properties and kinetic study0 aHydroformylation of 1octene using BmimPF6decane biphasic media a  a1155 16TH ST, NW, WASHINGTON, DC 20036 USAbAMER CHEMICAL SOCcNOV  a10698-107060 v493 a<p>A chemical reaction engineering approach is reported to investigate the biphasic hydroformylation of I-octene using [bmim][PF6] ionic liquid. It is based both on a process parameter investigation (temperature, concentrations, and pressures) and a thermodynamic study of the reaction medium (gas liquid and liquid liquid equilibria). Initial rate data show complex behavior with respect to operating parameters and are best described by a rate equation based on a mechanistic model. Complete reaction scheme including isomerization is then modeled accounting from the time dependent concentration of the organic substrates measured in organic phase and recalculated in ionic liquid phase from liquid liquid equilibria.</p>1 aSharma, Amit1 aLebigue, Carine, Julcour1 aDeshpande, Raj, Madhukar1 aKelkar, Ashutosh, A.1 aDelmas, Henri  uhttps://library.ncl.res.in/content/hydroformylation-1-octene-using-bmimpf6-decane-biphasic-media-and-rhodium-complex-catalyst-0