01643nas a2200169   4500008004100000022001400041245012100055210006900176260007100245300001600316490000800332520093300340100002101273700001901294700003001313856013001343       2010                        eng d  a1932-744700aFacile synthesis of N- and S-incorporated nanocrystalline TiO2 and direct solar-light-driven photocatalytic activity0 aFacile synthesis of N and Sincorporated nanocrystalline TiO2 and  a1155 16TH ST, NW, WASHINGTON, DC 20036 USAbAMER CHEMICAL SOCcNOV  a19473-194820 v1143 a<p>Sulfur- and nitrogen-incorporated mesoporous TiO2 (SNT) nanocomposites have been synthesized by a template-free homogeneous coprecipitation technique. The above nanocomposites have been thoroughly characterized by physicochemical and spectroscopy methods to explore the structural, electronic, and optical properties. The photocatalytic activities of the catalysts were evaluated for the degradation of methyl orange and phenol under direct solar light. SNT shows about a 2-fold higher photocatalytic activity than singly N-doped or S-doped mesoporous TiO2 and 3-fold higher than Degussa P25. The higher activity might be attributed to the synergetic interaction of sulfate and nitrogen with the TiO2 lattice. N-Ti-O and O-Ti-N-O environments are responsible for a red shift, and the sulfate group on TiO2 acts as a cocatalyst, for increasing surface acidity as well as for sustaining the redox cycles for high stability.</p>1 aNaik, Brundabana1 aParida, K., M.1 aGopinath, Chinnakonda, S.  uhttps://library.ncl.res.in/content/facile-synthesis-n-and-s-incorporated-nanocrystalline-tio2-and-direct-solar-light-driven-0