01301nas a2200169   4500008004100000022001400041245012800055210006900183260011000252300001400362490000700376520056200383100001700945700002100962700002000983856012801003       2011                        eng d  a1359-734500aTemplate induced structural isomerism and enhancement of porosity in manganese(II) based metal-organic frameworks (Mn-MOFs)0 aTemplate induced structural isomerism and enhancement of porosit  aTHOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLANDbROYAL SOC CHEMISTRYcJUN  a7674-76760 v473 a<p>Three new metal-organic framework isomers have been synthesized by using the organic linker 5-triazole isophthalic acid and Mn(NO3)(2)center dot xH(2)O. Structural conversions from non-porous to porous MOFs due to the template effect have been observed. The cross-sectional pore apertures of the resulting Mn-MOFs are comparable to the molecular dimensions of the template (pyrazine and 4,40-bipyridine). The periodic increased porosity in Mn-MOFs depending on the size of the template used has been further confirmed by the CO2 adsorption isotherms.</p>1 aPanda, Tamas1 aPachfule, Pradip1 aBanerjee, Rahul  uhttps://library.ncl.res.in/content/template-induced-structural-isomerism-and-enhancement-porosity-manganeseii-based-metal-0