02005nas a2200157   4500008004100000022001400041245017700055210006900232260007600301300001200377490000700389520127500396100002501671700002301696856012801719       2011                        eng d  a0032-388800aEffect of blend composition and organoclay loading on the nanocomposite structure and properties of miscible poly(methyl methacrylate)/poly(styrene-co-acrylonitrile) blends0 aEffect of blend composition and organoclay loading on the nanoco  aCOMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USAbWILEY-BLACKWELLcMAY  a979-9910 v513 a<p>Organically-modified montmorillonite clay nanocomposites of poly(styrene-co-acrylonitrile) (SAN), poly(methyl methacrylate) (PMMA) and SAN/PMMA miscible blend are investigated. Structure characteristics at the nanoscale and microscale and thermal and tensile properties are studied as a function of polymer blend composition and filler loading fraction. Blend miscibility and T(g) are unaffected by up to 10% by wt. organoclay. Thermal degradation stability increases with SAN content and exhibits an optimum value of clay loading. Stiffness shows significant improvement. Tensile strength and elongation-at-break suffer as a result of nanocomposite formation. Modulus shows a maximum enhancement of 57% (5 +/- 0.06 GPa at 10 wt% filler, 20/80 SAN/PMMA) and varies linearly with clay fraction for all compositions of matrix phase. Predictions of Halpin-Tsai composite model are in excellent agreement with the experimental behavior over full range of polymer blend composition. Fundamental aspects of a polymer blend-clay nanocomposite are clarified, such as lack of additional synergy between clay platelets and matrix, and tensile ductility reduction, compared with polymer-clay system. POLYM. ENG. SCI., 51:979-991, 2011. (C) 2011 Society of Plastics Engineers</p>1 aTiwari, Rajkiran, R.1 aNatarajan, Upendra  uhttps://library.ncl.res.in/content/effect-blend-composition-and-organoclay-loading-nanocomposite-structure-and-properties-0