01288nas a2200157   4500008004100000022001400041245010400055210006900159260007100228300001400299490000700313520064100320100002100961700002000982856012801002       2011                        eng d  a1528-748300aPorous nitrogen rich cadmium-tetrazolate based metal organic framework (MOF) for H-2 and CO2 uptake0 aPorous nitrogen rich cadmiumtetrazolate based metal organic fram  a1155 16TH ST, NW, WASHINGTON, DC 20036 USAbAMER CHEMICAL SOCcDEC  a5176-51810 v113 a<p>The highly porous nitrogen rich metal organic framework [Cd-3(4-TP)(6)] (Cd-4TP-1) was synthesized solvothermally from the predesigned organic building block 4-tetrazole pyridine (4-TP) and Cd(II) as metal center using DMF as solvent. Cd-4TP-1 has a three-dimensional porous architecture where all the binding sites of Cd(II) are exclusively occupied by the nitrogen atoms from the mu(2)-tetrazolyl group or the pyridyl functionality of the 4-TP ligands. Cd-4TP-1 has Brunauer-Emmett-Teller (BET) and Langmuir surface areas of 472.2 and 728.6 m(2)/g, respectively, and shows 1.1 wt % H-2 (77 K) and 2.7 mmol/g CO2 uptake (273 K).</p>1 aPachfule, Pradip1 aBanerjee, Rahul  uhttps://library.ncl.res.in/content/porous-nitrogen-rich-cadmium-tetrazolate-based-metal-organic-framework-mof-h-2-and-co2-0