01702nas a2200253   4500008004100000022001400041245015800055210006900213260007700282300001200359490000700371520072600378653001501104653002101119653001501140653003001155653003001185100002101215700002401236700002401260700002401284700002001308856012001328       2013                        eng d  a0947-653900aPorous-organic-framework-templated nitrogen-rich porous carbon as a more proficient electrocatalyst than Pt/C for the electrochemical reduction of oxygen0 aPorousorganicframeworktemplated nitrogenrich porous carbon as a   aBOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANYbWILEY-V C H VERLAG GMBHcJAN  a974-9800 v193 a<p>Porous nitrogen-rich carbon (POF-C-1000) that was synthesized by using a porous organic framework (POF) as a self-sacrificing host template in a nanocasting process possessed a high degree of graphitization in an ordered structural arrangement with large domains and well-ordered arrays of carbon sheets. POF-C-1000 exhibits favorable electrocatalytic activity for the oxygen-reduction reaction (ORR) with a clear positive shift of about 40 mV in the onset potential compared to that of a traditional, commercially available Pt/C catalyst. In addition, irrespective of its moderate surface area (785 m2?g-1), POF-C-1000 showed a reasonable H2 adsorption of 1.6 wt?% (77 K) and a CO2 uptake of 3.5 mmol?g-1 (273 K).</p>10aAdsorption10aElectrochemistry10afuel cells10aoxygen-reduction reaction10aporous organic frameworks1 aPachfule, Pradip1 aDhavale, Vishal, M.1 aKandambeth, Sharath1 aKurungot, Sreekumar1 aBanerjee, Rahul  uhttps://library.ncl.res.in/content/porous-organic-framework-templated-nitrogen-rich-porous-carbon-more-proficient-0