01329nas a2200157   4500008004100000022001400041245009100055210006900146260010600215300001400321490000700335520065500342100002500997700002801022856012101050       2013                        eng d  a0957-416600aBase-catalyzed mukaiyama-type aldol additions, a continued quest for stereoselectivity0 aBasecatalyzed mukaiyamatype aldol additions a continued quest fo  aTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLANDbPERGAMON-ELSEVIER SCIENCE LTDcNOV  a1345-13630 v243 a<p>Base-catalyzed reactions of silyl enolates with carbonyl compounds are an attractive variant of conventional directed aldol reactions. Over the past two decades, the reaction has gained prominence due to its inherent advantage for stereoselective manipulations. The present review provides a brief account of developments in this area. Various approaches are grouped together in order to provide the salient features of each conceptual development. It appears that the methods which generate nascent chiral enolates or cationic siliconium species have the biggest influence on the stereoselectivity. (C) 2013 Elsevier Ltd. All rights reserved.</p>1 aSutar, Revannath, L.1 aJoshi, Navalkishore, N.  uhttps://library.ncl.res.in/content/base-catalyzed-mukaiyama-type-aldol-additions-continued-quest-stereoselectivity-0