01863nas a2200253   4500008004100000022001400041245010900055210006900164260007700233300001400310490000700324520092400331653002501255653001501280653002901295653002101324653002201345100002501367700002501392700002001417700002401437700002101461856012701482       2014                        eng d  a1433-785100aTwo-in-one: inherent anhydrous and water-assisted high proton conduction in a 3D metal-organic framework0 aTwoinone inherent anhydrous and waterassisted high proton conduc  aBOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANYbWILEY-V C H VERLAG GMBHcMAR  a2638-26420 v533 a<p>The development of solid-state proton-conducting materials with high conductivity that operate under both anhydrous and humidified conditions is currently of great interest in fuel-cell technology. A 3Dmetal-organic framework (MOF) with acid-base pairs in its coordination space that efficiently conducts protons under both anhydrous and humid conditions has now been developed. The anhydrous proton conductivity for this MOF is among the highest values that have been reported for MOF materials, whereas its water-assisted proton conductivity is comparable to that of the organic polymer Nafion, which is currently used for practical applications. Unlike other MOFs, which conduct protons either under anhydrous or humid conditions, this compound should represent a considerable advance in the development of efficient solid-state proton-conducting materials that work under both anhydrous and humid conditions.</p>10aconducting materials10afuel cells10ametal-organic frameworks10aporous materials10aproton conduction1 aNagarkar, Sanjog, S.1 aUnni, SreeKuttan, M.1 aSharma, Amitosh1 aKurungot, Sreekumar1 aGhosh, Sujit, K.  uhttps://library.ncl.res.in/content/two-one-inherent-anhydrous-and-water-assisted-high-proton-conduction-3d-metal-organic-0