01439nas a2200205   4500008004100000022001400041245012400055210006900179260007100248300001400319490000700333520063300340100001800973700002500991700002101016700002001037700002401057700002101081856013101102       2015                        eng d  a0020-166900aCoherent fusion of water array and protonated amine in a metal-sulfate-based coordination polymer for proton conduction0 aCoherent fusion of water array and protonated amine in a metalsu  a1155 16TH ST, NW, WASHINGTON, DC 20036 USAbAMER CHEMICAL SOCcJUN  a5366-53710 v543 a<p>A new function of metal-sulfate-based co-ordination polymer (CP) for proton,conduction Was investigated through rational integration of a continuous water array and protonated amine in the coordination space of the CP. The H-bonded arrays of watet molecules along with nitrogen-rich aromatic cation (protonated melamine) facilitate proton conduction in the compound under humid conditions. Although several reports of metal-oxalate/phosphate-based CPs showing proton conduction are known, this is the first designed synthesis of a metal sulfate-based CP bearing-Water arrays functioning as a solid-state proton conductor:</p>1 aManna, Biplab1 aAnothumakkool, Bihag1 aDesai, Aamod, V.1 aSamanta, Partha1 aKurungot, Sreekumar1 aGhosh, Sujit, K.  uhttps://library.ncl.res.in/content/coherent-fusion-water-array-and-protonated-amine-metal-sulfate-based-coordination-polymer-0