01314nas a2200217   4500008004100000022001400041245008400055210006900139260010600208300001400314490000700328520047300335653002500808653004000833653001400873653002800887653002000915100002100935700002600956856011400982       2015                        eng d  a0040-403900aEfficient organocatalytic route for asymmetric total synthesis of stagonolide F0 aEfficient organocatalytic route for asymmetric total synthesis o  aTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLANDbPERGAMON-ELSEVIER SCIENCE LTDcNOV  a6207-62090 v563 a<p>A stereoselective total synthesis of Stagonolide F (98% ee) is described employing asymmetric alpha-aminooxylation, Jorgensen's asymmetric epoxidation, Brown asymmetric allylation, Steglich esterification and ring closing metathesis as key steps. The use of organocatalytic alpha-aminooxylation and Jorgensen's asymmetric epoxidation of aldehydes for the introduction of chirality makes this approach more attractive. (C) 2015 Elsevier Ltd. All rights reserved.</p>10aalpha-Aminooxylation10aJorgensens's asymmetric epoxidation10aMacrolide10aRing-closing metathesis10aTotal synthesis1 aShelke, Anil, M.1 aSuryavanshi, Gurunath  uhttps://library.ncl.res.in/content/efficient-organocatalytic-route-asymmetric-total-synthesis-stagonolide-f-0