@article {44238,
	title = {Transition-metal-catalyzed reactions involving arynes},
	journal = {Synthesis-Stuttgart},
	volume = {50},
	year = {2018},
	month = {JAN},
	pages = {1-16},
	type = {Article},
	abstract = {<p>The plethora of transformations attainable by the transition-metal-catalyzed reactions of arynes has found immense contemporary interest in the scientific community. This review highlights the scope and importance of transition-metal-catalyzed aryne reactions in the field of synthetic organic chemistry reported to date. It covers transformations achieved by the combination of arynes and various transition metals, which provide a facile access to a biaryl motif, fused polycyclic aromatic compounds, different novel carbocycles, various heterocycles, and complex natural products. 1 Introduction 2 Insertion of Arynes 3 Annulation of Arynes 4 Cycloaddition of Arynes 5 Multicomponent Reactions of Arynes 6 Miscellaneous Reactions of Arynes 7 Total Synthesis of Natural Products Using Arynes 8 Conclusion</p>},
	keywords = {annulation, arynes, Cycloaddition, Insertion, multicomponent, Natural products, Transition Metal},
	issn = {0039-7881},
	doi = {10.1055/s-0036-1589517},
	author = {Dhokale, Ranjeet A. and Mhaske, Santosh B.}
}
@article {46822,
	title = {Rapid synthesis of zwitterionic phosphonium benzoates by a three-component coupling involving phosphines, arynes and CO2},
	journal = {Chemistry-An Asian Journal},
	volume = {15},
	year = {2020},
	month = {JUL},
	pages = {2203-2207},
	type = {Article},
	abstract = {<p>A mild and easy to perform multicomponent coupling involving phosphines, arynes generated from 2-(trimethylsilyl)aryl triflates, and CO(2)allowing the transition-metal-free synthesis of zwitterionic phosphonium benzoates has been developed. The reaction proceeds via the generation of 1 : 1 zwitterionic intermediates from phosphines and arynes followed by the interception with CO(2)to deliver the carboxylates in moderate to good yields instead of the anticipated benzooxaphosphol-3(1H)-ones.</p>
},
	keywords = {arynes, Carbon dioxide, multicomponent coupling, Phosphines, zwitterions},
	issn = {1861-4728},
	doi = {10.1002/asia.202000610, Early Access Date = JUN 2020},
	author = {Bhattacharjee, Subrata and Raju, Anjali and Gaykar, Rahul N. and Gonnade, Rajesh G. and Roy, Tony and Biju, Akkattu T.}
}
