@article { ISI:000240352900023,
	title = {Ossification: a new approach to immobilize metal complex catalysts - applications to carbonylation and Suzuki coupling reactions},
	journal = {Journal of Catalysis},
	volume = {242},
	number = {1},
	year = {2006},
	month = {AUG},
	pages = {231-238},
	publisher = {ACADEMIC PRESS INC ELSEVIER SCIENCE},
	type = {Article},
	address = {525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA},
	abstract = {<p>A simple approach for immobilization of transition metal complexes is reported here based on the transformation of the complex into its intrinsically insoluble counterpart, thus generating solid molecular catalysts. This approach that we call {\textquoteleft}{\textquoteleft}ossification{\textquoteright}{\textquoteright} is based on a principle, in which the water-soluble analogues of the metal complexes are precipitated out from aqueous solutions as insoluble ionic ensembles having catalytically active metal-centered coordination environments and robust framework. The approach has been illustrated for I{\textquoteright}d complex catalyzed carbonylation and Suzuki coupling reactions. {\textquoteleft}{\textquoteleft}Ossification{\textquoteright}{\textquoteright} was found to be an economically and environmentally attractive alternative to other exotic immobilization methodologies. (c) 2006 Elsevier Inc. All rights reserved.</p>},
	keywords = {Carbonylation, Heterogeneous catalysts, Immobilization, ossification, Palladium complex, Suzuki coupling},
	issn = {0021-9517},
	doi = {10.1016/j.jcat.2006.05.032},
	author = {Sarkar, Bibhas R. and Chaudhari, Raghunath V.}
}
@article {45489,
	title = {Kinetics of hydroformylation of 1-decene using carbon-supported ossified HRh(CO)(TPPTS)(3) catalyst},
	journal = {International Journal of Chemical Kinetics},
	volume = {51},
	year = {2019},
	month = {FEB},
	pages = {112-122},
	type = {Article},
	abstract = {<p>The kinetics of hydroformylation of 1-decene has been investigated using a carbon-supported ossified HRh(CO)(TPPTS)(3)/Ba catalyst in a temperature range of 343-363 K. The effect of concentration of 1-decene, catalyst loading, partial pressure of H-2 and CO, and stirring speed on the reaction rate has been investigated. A first-order dependence was observed for catalyst concentration and hydrogen partial pressure. The rate showed a typical case of substrate inhibition for high 1-decene concentration. The rate varied with a linear dependence on P-CO up to a CO partial pressure of 5-6 MPa in contrast to the general trends; for most of the rhodium-phosphine catalyzed hydroformylation reactions, severe inhibition of rate is observed with an increase in CO pressure. A rate equation has been proposed, which was found to be in good agreement with the observed rate data within the limit of experimental errors. The kinetic parameters and activation energy values have been reported.</p>},
	keywords = {1-decene, Hydroformylation, kinetics, ossification, supported ossified},
	issn = {0538-8066},
	doi = {10.1002/kin.21234},
	author = {Pagar, Nitin S. and Deshpande, Raj M.}
}
