@article { ISI:000244183400009,
	title = {[SbW9O33]-based polyoxometalate combined with a phase transfer catalyst: A highly effective catalyst system for selective oxidation of alcohols with H2O2, and spectroscopic investigation},
	journal = {Journal of Molecular Catalysis A-Chemical},
	volume = {262},
	number = {1-2},
	year = {2007},
	month = {FEB},
	pages = {52-58},
	publisher = {ELSEVIER SCIENCE BV},
	type = {Article},
	address = {PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS},
	abstract = {<p>Na-9[SbW9O33] in conjunction with a phase transfer catalyst, methyltricapryl ammonium chloride, is highly efficient for selective oxidation of variety of alcohols with aq. H2O2 to yield corresponding carbonyls. Most importantly the reactions are carried out in the absence of any organic solvents especially halogenated solvents. In case of allylic alcohols, the catalyst is highly selective for the alcohol oxidation reaction and least selective for epoxidation reaction in the presence of aq. H2O2. IR studies support the formation of W-peroxo intermediate species and also support the stability of the catalyst in the presence of phase transfer compound under the present experimental condition. The catalyst can be reused after careful decomposition of peroxide of the final reaction mixture. (c) 2006 Elsevier B.V. All rights reserved.</p>},
	keywords = {Alcohol, Aq.H2O2, Nag[SbW9O33], Oxidation, Phase transfer catalyst, Polyoxometalate, polyoxotungstate},
	issn = {1381-1169},
	doi = {10.1016/j.molcata.2006.08.050},
	author = {Ingle, Rohit H. and Raj, N. K. Kala and Manikandan, Palanichamy}
}
@article { ISI:000347265700005,
	title = {Characterization, non-isothermal decomposition kinetics and photocatalytic water splitting of green chemically synthesized polyoxoanions of molybdenum containing phosphorus as hetero atom},
	journal = {Thermochimica Acta},
	volume = {596},
	year = {2014},
	month = {NOV},
	pages = {29-36},
	publisher = {ELSEVIER SCIENCE BV},
	type = {Article},
	address = {PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS},
	abstract = {<p>In here, the green synthesis and thermal characterization of a novel polyoxoanions of molybdenum containing phosphorus as hetero atom are reported. The composition and morphology of the nanorods were established by fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA) and inductively coupled plasma atomic emission spectroscopic (ICP-AES) techniques. Thermal properties of the nanoparticles were investigated by non-isothermal analysis under nitrogen atmosphere. The values activation energy of each stage of thermal decomposition for all heating rates was calculated by Flynn-Wall-Ozawa (FWO) and Kissinger-Akahira-Sunnose (KAS) methods. Invariant kinetic parameter (IKP) method and master plot methodmere also used to evaluate the kinetic parameters and mechanism for the thermal decomposition of cetylpyridinium phosphomolybdate (CPM). Photocatalytic water oxidation mechanism using CPM catalyst in the presence of platinum (Pt) co-catalyst enhances the H-2 evolution and was found to be 1.514 mmol/g/h. (C) 2014 Elsevier B.V. All rights reserved.</p>},
	keywords = {Keggin structure, Master plot method, Polyoxometalate, Water oxidation},
	issn = {0040-6031},
	doi = {10.1016/j.tca.2014.09.010},
	author = {D{\textquoteright}Cruz, Bessy and Samuel, Jadu and George, Leena}
}
